Orientation-induced redox isomerism in planar supramolecular systems
Vladimir V. Arslanov
1, 2
,
Yulia G. Gorbunova
1, 3
,
Kirill P. Birin
1
,
Oleg A. Raitman
1
,
F. Moroté
4
,
Fabien Morote
5
,
Touria Cohen-Bouhacina
4, 5
,
Christine Grauby-Heywang
4, 5
,
Aslan Tsivadze
1, 3
,
Aslan Yu. Tsivadze
2, 3
Publication type: Journal Article
Publication date: 2014-02-17
scimago Q1
wos Q3
SJR: 0.914
CiteScore: 6.2
Impact factor: 3.2
ISSN: 19327447, 19327455
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
General Energy
Abstract
In this work, a previously undescribed phenomenon of orientation-induced redox isomerism in a Langmuir monolayer is revealed in the case of cerium bis-[tetra-(15-crown-5)-phthalocyaninate]-(Ce[(15C5)4Pc]2). It was established that intramolecular electron transfer (IET) from the electronic system of phthalocyanine to the 4f-orbital of cerium atom occurs upon spreading of a (Ce[(15C5)4Pc]2) chloroform solution onto the air–water interface (3D → 2D IET). This process is related to the transformation of Ce4+ cation in the solution to Ce3+ in the monolayer. It was also found that reversible Ce3+ ↔ Ce4+ IETs occur upon compression (π1 → π2) and expansion (π2 → π1) of monolayer (2Dπ1 ↔ 2Dπ2 IET, π-surface pressure). The mechanism of genuine redox isomerism was confirmed by the results of in situ UV–vis spectral measurements performed on monolayers and Langmuir–Blodgett films, AFM, and XPS studies of Langmuir–Blodgett films transferred at different surface pressures. The understanding of this reversible IET mecha...
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Total citations:
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Citations from 2024:
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GOST
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Selektor S. L. et al. Orientation-induced redox isomerism in planar supramolecular systems // Journal of Physical Chemistry C. 2014. Vol. 118. No. 8. pp. 4250-4258.
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Selektor S. L., Shokurov A. V., Arslanov V. V., Gorbunova Y. G., Birin K. P., Raitman O. A., Moroté F., Morote F., Cohen-Bouhacina T., Grauby-Heywang C., Tsivadze A., Tsivadze A. Y. Orientation-induced redox isomerism in planar supramolecular systems // Journal of Physical Chemistry C. 2014. Vol. 118. No. 8. pp. 4250-4258.
Cite this
RIS
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TY - JOUR
DO - 10.1021/jp411936k
UR - https://pubs.acs.org/doi/10.1021/jp411936k
TI - Orientation-induced redox isomerism in planar supramolecular systems
T2 - Journal of Physical Chemistry C
AU - Selektor, Sofiya L.
AU - Shokurov, Alexander V.
AU - Arslanov, Vladimir V.
AU - Gorbunova, Yulia G.
AU - Birin, Kirill P.
AU - Raitman, Oleg A.
AU - Moroté, F.
AU - Morote, Fabien
AU - Cohen-Bouhacina, Touria
AU - Grauby-Heywang, Christine
AU - Tsivadze, Aslan
AU - Tsivadze, Aslan Yu.
PY - 2014
DA - 2014/02/17
PB - American Chemical Society (ACS)
SP - 4250-4258
IS - 8
VL - 118
SN - 1932-7447
SN - 1932-7455
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Selektor,
author = {Sofiya L. Selektor and Alexander V. Shokurov and Vladimir V. Arslanov and Yulia G. Gorbunova and Kirill P. Birin and Oleg A. Raitman and F. Moroté and Fabien Morote and Touria Cohen-Bouhacina and Christine Grauby-Heywang and Aslan Tsivadze and Aslan Yu. Tsivadze},
title = {Orientation-induced redox isomerism in planar supramolecular systems},
journal = {Journal of Physical Chemistry C},
year = {2014},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://pubs.acs.org/doi/10.1021/jp411936k},
number = {8},
pages = {4250--4258},
doi = {10.1021/jp411936k}
}
Cite this
MLA
Copy
Selektor, Sofiya L., et al. “Orientation-induced redox isomerism in planar supramolecular systems.” Journal of Physical Chemistry C, vol. 118, no. 8, Feb. 2014, pp. 4250-4258. https://pubs.acs.org/doi/10.1021/jp411936k.