New Insight into Photochemistry of Ferrioxalate
Ivan P Pozdnyakov
1
,
Oksana V Kel
1
,
Victor F. Plyusnin
1
,
Vjacheslav P. Grivin
1
,
Nikolai M Bazhin
1
Publication type: Journal Article
Publication date: 2008-08-15
scimago Q2
wos Q2
SJR: 0.634
CiteScore: 4.8
Impact factor: 2.8
ISSN: 10895639, 15205215
PubMed ID:
18707071
Physical and Theoretical Chemistry
Abstract
Optical spectroscopy and nanosecond flash photolysis (Nd:YAG laser, 355 nm, pulse duration 5 ns, mean energy 5 mJ/pulse) were used to study the photochemistry of FeIII(C2O4)33− complex in aqueous solutions. The main photochemical process was found to be intramolecular electron transfer from the ligand to Fe(III) ion with formation of a primary radical complex [(C2O4)2FeII(C2O4•)]3−. The yield of radical species (i.e., CO2• − and C2O4• −) was found to be less than 6% of FeIII(C2O4)33− disappeared after flash. [(C2O4)2FeII(C2O4•)]3− dissociates reversibly into oxalate ion and a secondary radical complex, [(C2O4)FeII(C2O4•)]−. The latter reacts with the initial complex and dissociates to FeII(C2O4) and oxalate radical. In this framework, the absorption spectra and rate constants of the reactions of all intermediates were determined.
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GOST
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P Pozdnyakov I. et al. New Insight into Photochemistry of Ferrioxalate // Journal of Physical Chemistry A. 2008. Vol. 112. No. 36. pp. 8316-8322.
GOST all authors (up to 50)
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P Pozdnyakov I., Kel O. V., Plyusnin V. F., Grivin V. P., Bazhin N. M. New Insight into Photochemistry of Ferrioxalate // Journal of Physical Chemistry A. 2008. Vol. 112. No. 36. pp. 8316-8322.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jp8040583
UR - https://doi.org/10.1021/jp8040583
TI - New Insight into Photochemistry of Ferrioxalate
T2 - Journal of Physical Chemistry A
AU - P Pozdnyakov, Ivan
AU - Kel, Oksana V
AU - Plyusnin, Victor F.
AU - Grivin, Vjacheslav P.
AU - Bazhin, Nikolai M
PY - 2008
DA - 2008/08/15
PB - American Chemical Society (ACS)
SP - 8316-8322
IS - 36
VL - 112
PMID - 18707071
SN - 1089-5639
SN - 1520-5215
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_P Pozdnyakov,
author = {Ivan P Pozdnyakov and Oksana V Kel and Victor F. Plyusnin and Vjacheslav P. Grivin and Nikolai M Bazhin},
title = {New Insight into Photochemistry of Ferrioxalate},
journal = {Journal of Physical Chemistry A},
year = {2008},
volume = {112},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/jp8040583},
number = {36},
pages = {8316--8322},
doi = {10.1021/jp8040583}
}
Cite this
MLA
Copy
P. Pozdnyakov, Ivan, et al. “New Insight into Photochemistry of Ferrioxalate.” Journal of Physical Chemistry A, vol. 112, no. 36, Aug. 2008, pp. 8316-8322. https://doi.org/10.1021/jp8040583.