Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22.
Elena N Golubeva
1
,
Dmitry N Kharitonov
1
,
Dmitry I Kochubey
1
,
Vladimir N Ikorskii
1
,
Vladimir V Kriventsov
1
,
Julia Stoetsner
1
,
Detlef W. Bahnemann
1
Publication type: Journal Article
Publication date: 2009-08-17
scimago Q2
wos Q2
SJR: 0.634
CiteScore: 4.8
Impact factor: 2.8
ISSN: 10895639, 15205215
PubMed ID:
19685912
Physical and Theoretical Chemistry
Abstract
Transformations of anionic Cu(II) chlorocomplexes have been studied under conditions of catalytic exchange reactions between carbon tetrachloride and n-alkanes. It was shown that chlorocuprates are just precursors and are easily reduced to the genuine catalysts, that is, to the respective Cu(I) complexes. Both the composition and the geometric structure of the precursor (CuCl(4)(2-)) and, probably, the active site (CuCl(3)(2-)) have been investigated by several techniques (UV-vis spectroscopy, electron spin resonance (ESR), extended X-ray absorption fine structure (EXAFS), X-ray absorption near-edge structure (XANES), and static magnetic measurements). The dependence of the metathesis velocity on the [Cl-]/[Cu] ratio was found to exhibit a maximum most likely corresponding to the highest content of trichlorocuprite CuCl(3)(2-).
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Total citations:
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Golubeva E. N. et al. Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22. // Journal of Physical Chemistry A. 2009. Vol. 113. No. 38. pp. 10219-10223.
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Golubeva E. N., Kharitonov D. N., Kochubey D. I., Ikorskii V. N., Kriventsov V. V., Kokorin A. I., Stoetsner J., Bahnemann D. W. Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22. // Journal of Physical Chemistry A. 2009. Vol. 113. No. 38. pp. 10219-10223.
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RIS
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TY - JOUR
DO - 10.1021/jp900742r
UR - https://doi.org/10.1021/jp900742r
TI - Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22.
T2 - Journal of Physical Chemistry A
AU - Golubeva, Elena N
AU - Kharitonov, Dmitry N
AU - Kochubey, Dmitry I
AU - Ikorskii, Vladimir N
AU - Kriventsov, Vladimir V
AU - Kokorin, Alexander I.
AU - Stoetsner, Julia
AU - Bahnemann, Detlef W.
PY - 2009
DA - 2009/08/17
PB - American Chemical Society (ACS)
SP - 10219-10223
IS - 38
VL - 113
PMID - 19685912
SN - 1089-5639
SN - 1520-5215
ER -
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BibTex (up to 50 authors)
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@article{2009_Golubeva,
author = {Elena N Golubeva and Dmitry N Kharitonov and Dmitry I Kochubey and Vladimir N Ikorskii and Vladimir V Kriventsov and Alexander I. Kokorin and Julia Stoetsner and Detlef W. Bahnemann},
title = {Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22.},
journal = {Journal of Physical Chemistry A},
year = {2009},
volume = {113},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/jp900742r},
number = {38},
pages = {10219--10223},
doi = {10.1021/jp900742r}
}
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Golubeva, Elena N., et al. “Formation of active catalysts in the system: chlorocuprates-CCl4-n-C10H22..” Journal of Physical Chemistry A, vol. 113, no. 38, Aug. 2009, pp. 10219-10223. https://doi.org/10.1021/jp900742r.
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