volume 100 issue 6 pages 2154-2160

Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+

Publication typeJournal Article
Publication date1996-01-01
SJR
CiteScore
Impact factor
ISSN00223654, 15415740
Physical and Theoretical Chemistry
General Engineering
Abstract
The complexation of the derivatives of crown ether styryl dyes betaine 2-[2-(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-16-yl)ethenyl]-3-(3-sulfopropyl)benzothiazolium (1a) and perchlorate 2-[2-(2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin-16-yl)ethenyl]-3-ethylbenzothiazolium (1b) and their molecular fragment 2,3,5,6,8,9,11,12-octahydro-1,4,7,10,13-benzopentaoxacyclopentadecin (2) with magnesium cations has been studied by the surface-enhanced Raman scattering (SERS) spectroscopy at very low (down to 10-8 M) concentrations. A detailed comparison of the Raman and SERS spectra of 1a,b and their molecular fragments 2 and perchlorate 2-Me-3-ethyl benzothiazolium (3) enabled one to assign the vibrational modes and propose the model of dye interaction with the silver SERS-active surface. Benzo-15-crown-5 chromophore of 1a,b was found to be adsorbed through its crown ether part so that the plane of benzene ring is nearly perpendicular to the surface of silver el...
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Feofanov A. V. et al. Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+ // The Journal of Physical Chemistry. 1996. Vol. 100. No. 6. pp. 2154-2160.
GOST all authors (up to 50) Copy
Feofanov A. V., Alexey F., Ianoul A., Oleinikov V., Fomina M. V., Gromov S., Федорова О. С., Fedorova O., Alfimov M., Nabiev I., Nabiev I. Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+ // The Journal of Physical Chemistry. 1996. Vol. 100. No. 6. pp. 2154-2160.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jp9513024
UR - https://pubs.acs.org/doi/10.1021/jp9513024
TI - Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+
T2 - The Journal of Physical Chemistry
AU - Feofanov, A. V.
AU - Alexey, Feofanov
AU - Ianoul, Anatoli
AU - Oleinikov, Vladimir
AU - Fomina, Marina V.
AU - Gromov, Sergey
AU - Федорова, О. С.
AU - Fedorova, Olga
AU - Alfimov, Michail
AU - Nabiev, I.R.
AU - Nabiev, Igor
PY - 1996
DA - 1996/01/01
PB - American Chemical Society (ACS)
SP - 2154-2160
IS - 6
VL - 100
SN - 0022-3654
SN - 1541-5740
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1996_Feofanov,
author = {A. V. Feofanov and Feofanov Alexey and Anatoli Ianoul and Vladimir Oleinikov and Marina V. Fomina and Sergey Gromov and О. С. Федорова and Olga Fedorova and Michail Alfimov and I.R. Nabiev and Igor Nabiev},
title = {Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+},
journal = {The Journal of Physical Chemistry},
year = {1996},
volume = {100},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://pubs.acs.org/doi/10.1021/jp9513024},
number = {6},
pages = {2154--2160},
doi = {10.1021/jp9513024}
}
MLA
Cite this
MLA Copy
Feofanov, A. V., et al. “Surface-enhanced resonance raman spectra of photochromic crown ether styryl dyes, their model chromophores, and their complexes with Mg2+.” The Journal of Physical Chemistry, vol. 100, no. 6, Jan. 1996, pp. 2154-2160. https://pubs.acs.org/doi/10.1021/jp9513024.