Determination of End-to-End Distances in Oligomers by Pulsed EPR
Тип публикации: Journal Article
Дата публикации: 1996-01-01
SJR: 1.641
CiteScore: —
Impact factor: —
ISSN: 00223654, 15415740
Physical and Theoretical Chemistry
General Engineering
Краткое описание
Conformations of end-labeled alkanes in a rigid polymer matrix were investigated using the pulsed double electron-electron resonance (DEER) method. To this end, dipolar spectra of a series of aliphatic dicarbonic acids with 8−20 methylene units and chain ends bifunctionalized with nitroxide radicals were recorded in a polystyrene matrix. The biradicals are derived from hindered amine light stabilizers (HALS), used as polymer additives. Analysis of the dipolar spectra allows the determination of the end-to-end distances of the oligomer biradicals. The experiments show that the “flexible” alkane chains are almost completely stretched. This observation is consistent with the results of force field calculations.
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ГОСТ
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Pfannebecker V. et al. Determination of End-to-End Distances in Oligomers by Pulsed EPR // The Journal of Physical Chemistry. 1996. Vol. 100. No. 32. pp. 13428-13432.
ГОСТ со всеми авторами (до 50)
Скопировать
Pfannebecker V., Klos H., Hubrich M., Volkmer T., Heuer A., Wiesner U., Spiess H. Determination of End-to-End Distances in Oligomers by Pulsed EPR // The Journal of Physical Chemistry. 1996. Vol. 100. No. 32. pp. 13428-13432.
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RIS
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TY - JOUR
DO - 10.1021/jp960895v
UR - https://doi.org/10.1021/jp960895v
TI - Determination of End-to-End Distances in Oligomers by Pulsed EPR
T2 - The Journal of Physical Chemistry
AU - Pfannebecker, V
AU - Klos, H
AU - Hubrich, M
AU - Volkmer, T
AU - Heuer, Andreas
AU - Wiesner, Ulrich
AU - Spiess, H.W.
PY - 1996
DA - 1996/01/01
PB - American Chemical Society (ACS)
SP - 13428-13432
IS - 32
VL - 100
SN - 0022-3654
SN - 1541-5740
ER -
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BibTex (до 50 авторов)
Скопировать
@article{1996_Pfannebecker,
author = {V Pfannebecker and H Klos and M Hubrich and T Volkmer and Andreas Heuer and Ulrich Wiesner and H.W. Spiess},
title = {Determination of End-to-End Distances in Oligomers by Pulsed EPR},
journal = {The Journal of Physical Chemistry},
year = {1996},
volume = {100},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jp960895v},
number = {32},
pages = {13428--13432},
doi = {10.1021/jp960895v}
}
Цитировать
MLA
Скопировать
Pfannebecker, V., et al. “Determination of End-to-End Distances in Oligomers by Pulsed EPR.” The Journal of Physical Chemistry, vol. 100, no. 32, Jan. 1996, pp. 13428-13432. https://doi.org/10.1021/jp960895v.
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