Effect of Hydrophobicity of Amino Acids on the Structure of Water
Тип публикации: Journal Article
Дата публикации: 1997-08-01
SCImago Q1
WOS Q3
БС2
SJR: 0.785
CiteScore: 5
Impact factor: 3.2
ISSN: 15206106, 15205207, 10895647
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Краткое описание
The structure of water in various amino acid solutions was examined by Raman spectroscopy and 1H NMR. Analyses of the relative intensity (C value) of the O−H stretching Raman band corresponding to an in-phase collective vibration of O−H oscillators that are connected by hydrogen bonds revealed that the structure of water in solutions of various amino acids (Gly, Ala, Ser, Val, Leu, Ile, His, Asn) at neutral pH did not differ from one another significantly, which shows that the structure of water is little affected by the side chains. Deionization of carboxylate or ammonium ions induced appearance of the effects of side chains on the structure of water around them. That is, the structure of water in aqueous solutions of amino acids with nonpolar side chain was enhanced, and the probability of hydrogen bonding between water molecules increased by forming water clathrate around the side chain. On the other hand, the structure of water in the solutions of amino acids with polar or charged side chain was destr...
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Ide M., Maeda Y., Kitano H. Effect of Hydrophobicity of Amino Acids on the Structure of Water // Journal of Physical Chemistry B. 1997. Vol. 101. No. 35. pp. 7022-7026.
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Ide M., Maeda Y., Kitano H. Effect of Hydrophobicity of Amino Acids on the Structure of Water // Journal of Physical Chemistry B. 1997. Vol. 101. No. 35. pp. 7022-7026.
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TY - JOUR
DO - 10.1021/jp971334m
UR - https://doi.org/10.1021/jp971334m
TI - Effect of Hydrophobicity of Amino Acids on the Structure of Water
T2 - Journal of Physical Chemistry B
AU - Ide, Makoto
AU - Maeda, Yasushi
AU - Kitano, Hiromi
PY - 1997
DA - 1997/08/01
PB - American Chemical Society (ACS)
SP - 7022-7026
IS - 35
VL - 101
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
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@article{1997_Ide,
author = {Makoto Ide and Yasushi Maeda and Hiromi Kitano},
title = {Effect of Hydrophobicity of Amino Acids on the Structure of Water},
journal = {Journal of Physical Chemistry B},
year = {1997},
volume = {101},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/jp971334m},
number = {35},
pages = {7022--7026},
doi = {10.1021/jp971334m}
}
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MLA
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Ide, Makoto, et al. “Effect of Hydrophobicity of Amino Acids on the Structure of Water.” Journal of Physical Chemistry B, vol. 101, no. 35, Aug. 1997, pp. 7022-7026. https://doi.org/10.1021/jp971334m.
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