том 4 издание 12 страницы 2015-2020

Quantum behavior of water molecules confined to nanocavities in gemstones

Тип публикацииJournal Article
Дата публикации2013-06-03
scimago Q1
wos Q1
БС1
SJR1.394
CiteScore8.7
Impact factor4.6
ISSN19487185
Physical and Theoretical Chemistry
General Materials Science
Краткое описание
When water is confined to nanocavities, its quantum mechanical behavior can be revealed by terahertz spectroscopy. We place H2O molecules in the nanopores of a beryl crystal lattice and observe a rich and highly anisotropic set of absorption lines in the terahertz spectral range. Two bands can be identified, which originate from translational and librational motions of the water molecule isolated within the cage; they correspond to the analogous broad bands in liquid water and ice. In the present case of well-defined and highly symmetric nanocavities, the observed fine structure can be explained by macroscopic tunneling of the H2O molecules within a six-fold potential caused by the interaction of the molecule with the cavity walls.
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ГОСТ |
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Gorshunov B. et al. Quantum behavior of water molecules confined to nanocavities in gemstones // Journal of Physical Chemistry Letters. 2013. Vol. 4. No. 12. pp. 2015-2020.
ГОСТ со всеми авторами (до 50) Скопировать
Gorshunov B., Zhukova E. S., Torgashev V. I., Lebedev V. S., Shakurov G. S., Kremer R. K., Pestrjakov E. V., Thomas V. G., Fursenko D. A., Dressel M. Quantum behavior of water molecules confined to nanocavities in gemstones // Journal of Physical Chemistry Letters. 2013. Vol. 4. No. 12. pp. 2015-2020.
RIS |
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TY - JOUR
DO - 10.1021/jz400782j
UR - https://doi.org/10.1021/jz400782j
TI - Quantum behavior of water molecules confined to nanocavities in gemstones
T2 - Journal of Physical Chemistry Letters
AU - Gorshunov, Boris
AU - Zhukova, Elena S.
AU - Torgashev, Victor I
AU - Lebedev, V. S.
AU - Shakurov, G. S.
AU - Kremer, Reinhard K.
AU - Pestrjakov, Efim V
AU - Thomas, V G
AU - Fursenko, Dimitry A
AU - Dressel, Martin
PY - 2013
DA - 2013/06/03
PB - American Chemical Society (ACS)
SP - 2015-2020
IS - 12
VL - 4
PMID - 26283245
SN - 1948-7185
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2013_Gorshunov,
author = {Boris Gorshunov and Elena S. Zhukova and Victor I Torgashev and V. S. Lebedev and G. S. Shakurov and Reinhard K. Kremer and Efim V Pestrjakov and V G Thomas and Dimitry A Fursenko and Martin Dressel},
title = {Quantum behavior of water molecules confined to nanocavities in gemstones},
journal = {Journal of Physical Chemistry Letters},
year = {2013},
volume = {4},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/jz400782j},
number = {12},
pages = {2015--2020},
doi = {10.1021/jz400782j}
}
MLA
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Gorshunov, Boris, et al. “Quantum behavior of water molecules confined to nanocavities in gemstones.” Journal of Physical Chemistry Letters, vol. 4, no. 12, Jun. 2013, pp. 2015-2020. https://doi.org/10.1021/jz400782j.