Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst
1
Materials Science and Engineering
Publication type: Journal Article
Publication date: 1993-06-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The reactivity of 5-hexenyl-9-BBN in Ziegler-Natta copolymerization with α-olefins, e.g., propylene, 1-butene, and 1-octene is investigated. The monomer reactivities were studied by reactivity ratio, copolymer compositions during the reaction and copolymer microstructure. In general, the borane monomer can be effectively incorporated into polyolefins with controllable concentrations and locations. Due to the excellent stability of boranes to the catalyst and solubility of boranes in hydrocarbon solution, the borane monomer behaves as a high α-olefin monomer in Ziegler-Natta polymerization. In turn, the trialkylboranes in copolymers are easily converted to various functional groups under homogeneous or heterogeneous reaction conditions
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GOST
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Chung T., Rhubright D. Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst // Macromolecules. 1993. Vol. 26. No. 12. pp. 3019-3025.
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Chung T., Rhubright D. Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst // Macromolecules. 1993. Vol. 26. No. 12. pp. 3019-3025.
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RIS
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TY - JOUR
DO - 10.1021/ma00064a004
UR - https://doi.org/10.1021/ma00064a004
TI - Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst
T2 - Macromolecules
AU - Chung, T.C.
AU - Rhubright, D
PY - 1993
DA - 1993/06/01
PB - American Chemical Society (ACS)
SP - 3019-3025
IS - 12
VL - 26
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
Copy
@article{1993_Chung,
author = {T.C. Chung and D Rhubright},
title = {Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst},
journal = {Macromolecules},
year = {1993},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ma00064a004},
number = {12},
pages = {3019--3025},
doi = {10.1021/ma00064a004}
}
Cite this
MLA
Copy
Chung, T.C., and D Rhubright. “Kinetic aspects of the copolymerization between .alpha.-olefins and borane monomer in Ziegler-Natta catalyst.” Macromolecules, vol. 26, no. 12, Jun. 1993, pp. 3019-3025. https://doi.org/10.1021/ma00064a004.