Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups
1
DuPont Central Research and Development, Experimental Station, P.O. Box 80328, Wilmington, Delaware 19880-0328
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Publication type: Journal Article
Publication date: 2000-10-31
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Styrenes with pendant lithium perfluoroalkyl ether sulfonate or sulfonimide groups readily homopolymerized and copolymerized with olefinic monomers to provide moderate to high molecular weight ionomers. Comonomers included styrene, methyl methacrylate, acrylonitrile, and acrylates. In addition, soluble polymers containing both mobile lithium ions and immobilized tetraalkylammonium cations were prepared. Cross-linked polymers were obtained by copolymerization of the functionalized styrenes with difunctional comonomers or by cocuring with an unsaturated elastomer. Polyesters with pendant lithium perfluoroalkylsulfonate groups were obtained by condensation polymerization of functionalized isophthalate monomers with bis(hydroxyethyl)terephthalate. Surprisingly, most of the ethylene glycol units in the polymers were converted into poly(ethylene glycol) segments during polymerization. Lithium ion conductivities of 10-4−10-3 S/cm were shown by selected polymers in solution or as solvent swollen films.
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Total citations:
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Citations from 2024:
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GOST
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Feiring A. E. et al. Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups // Macromolecules. 2000. Vol. 33. No. 25. pp. 9262-9271.
GOST all authors (up to 50)
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Feiring A. E., Choi S. K., Doyle M., Wonchoba E. R. Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups // Macromolecules. 2000. Vol. 33. No. 25. pp. 9262-9271.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma000893f
UR - https://doi.org/10.1021/ma000893f
TI - Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups
T2 - Macromolecules
AU - Feiring, Andrew E
AU - Choi, Susan K.
AU - Doyle, Marc
AU - Wonchoba, Edward R
PY - 2000
DA - 2000/10/31
PB - American Chemical Society (ACS)
SP - 9262-9271
IS - 25
VL - 33
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2000_Feiring,
author = {Andrew E Feiring and Susan K. Choi and Marc Doyle and Edward R Wonchoba},
title = {Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups},
journal = {Macromolecules},
year = {2000},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ma000893f},
number = {25},
pages = {9262--9271},
doi = {10.1021/ma000893f}
}
Cite this
MLA
Copy
Feiring, Andrew E., et al. “Novel Aromatic Polymers with Pendant Lithium Perfluoroalkylsulfonate or Sulfonimide Groups.” Macromolecules, vol. 33, no. 25, Oct. 2000, pp. 9262-9271. https://doi.org/10.1021/ma000893f.