Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System
Publication type: Journal Article
Publication date: 1994-07-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Copolymers of propylene and the polar monomer 6-tert-butyl-2-(1,1-dimethylhept-6-enyl)-4-methylphenol were obtained with racemic [1,1'-(dimethylsilylene)bis(η 5 -4,5,6,7-tetrahydro-1-indenyl)]-zirconium dichloride and methylalumoxane activator. The copolymers contained from 1.3 to 5.5 wt% of phenolic units and exhibited high thermooxidative stability even after prolonged extraction with a mixture of refluxing (50:50) 2-propanol/cyclohexane
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Wilén C., Näsman J. H. Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System // Macromolecules. 1994. Vol. 27. No. 15. pp. 4051-4057.
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Wilén C., Näsman J. H. Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System // Macromolecules. 1994. Vol. 27. No. 15. pp. 4051-4057.
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TY - JOUR
DO - 10.1021/ma00093a004
UR - https://doi.org/10.1021/ma00093a004
TI - Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System
T2 - Macromolecules
AU - Wilén, Carl-Eric
AU - Näsman, Jan H
PY - 1994
DA - 1994/07/01
PB - American Chemical Society (ACS)
SP - 4051-4057
IS - 15
VL - 27
SN - 0024-9297
SN - 1520-5835
ER -
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@article{1994_Wilén,
author = {Carl-Eric Wilén and Jan H Näsman},
title = {Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System},
journal = {Macromolecules},
year = {1994},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ma00093a004},
number = {15},
pages = {4051--4057},
doi = {10.1021/ma00093a004}
}
Cite this
MLA
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Wilén, Carl-Eric, and Jan H Näsman. “Polar Activation in Copolymerization of Propylene and 6-tert-Butyl-[2-(1,1-dimethylhept-6-enyl)]-4-methylphenol over a Racemic [1,1'-(Dimethylsilylene)bis(.eta.5-4,5,6,7-tetrahydro-1- indenyl)]zirconium Dichloride/Methylalumoxane Catalyst System.” Macromolecules, vol. 27, no. 15, Jul. 1994, pp. 4051-4057. https://doi.org/10.1021/ma00093a004.