Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions
Тип публикации: Journal Article
Дата публикации: 1994-07-01
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The aggregation and phase behavior in water of several triblock copolymers of poly(oxethylene)poly(oxypropylene)-poly(oxyethylene) [(EO) x (PO) y (EO) x ] has been studied. The y-values of the compounds ranged from 16 to 70 and the x:y ratios from 0.1 to 2.5. All studied compounds form micelles and lyotropic liquid crystalline phases. Fow constant temperature the critical micelle concentrations (cmc) of the compounds decrease exponentially with y. The energy increment for the transfer of a PO group from the aqueous to the micellar state is about (0.25±0.05) kT. The cmc values for all compounds decrease strongly with increasing temperature. As a consequence the solutions undergo a monomermicelle transition for constant concentration and increasing temperature
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Wanka G., Hoffmann H., Ulbricht W. Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions // Macromolecules. 1994. Vol. 27. No. 15. pp. 4145-4159.
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Wanka G., Hoffmann H., Ulbricht W. Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions // Macromolecules. 1994. Vol. 27. No. 15. pp. 4145-4159.
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TY - JOUR
DO - 10.1021/ma00093a016
UR - https://doi.org/10.1021/ma00093a016
TI - Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions
T2 - Macromolecules
AU - Wanka, G
AU - Hoffmann, H
AU - Ulbricht, W
PY - 1994
DA - 1994/07/01
PB - American Chemical Society (ACS)
SP - 4145-4159
IS - 15
VL - 27
SN - 0024-9297
SN - 1520-5835
ER -
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@article{1994_Wanka,
author = {G Wanka and H Hoffmann and W Ulbricht},
title = {Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions},
journal = {Macromolecules},
year = {1994},
volume = {27},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ma00093a016},
number = {15},
pages = {4145--4159},
doi = {10.1021/ma00093a016}
}
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Wanka, G., et al. “Phase Diagrams and Aggregation Behavior of Poly(oxyethylene)-Poly(oxypropylene)-Poly(oxyethylene) Triblock Copolymers in Aqueous Solutions.” Macromolecules, vol. 27, no. 15, Jul. 1994, pp. 4145-4159. https://doi.org/10.1021/ma00093a016.