Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts
Publication type: Journal Article
Publication date: 2011-10-19
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A novel class of living radical polymerization using amines as organic catalysts was developed. It is based on a new reversible activation mechanism, reversible complexation (RC). The polymer molecular weight and its distribution (Mw/Mn = 1.1–1.4) were well controlled in the polymerizations of methyl methacrylate (MMA), styrene, acrylonitrile, and some functional methacrylates with a fairly high conversion in hours in many cases. The catalysts include such common amines as triethylamine and tetramethylethylenediamine (TMEDA). Their low cost, good environmental safety, and ease of handling may be attractive for possible applications. Kinetic studies supported the RC mechanism. The activation rate constant for the MMA/TMEDA system was large enough to explain why the system provides low-polydispersity polymers from an early stage of polymerization.
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Metrics
135
Total citations:
135
Citations from 2024:
18
(13.34%)
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MLA
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GOST
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Goto A. et al. Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts // Macromolecules. 2011. Vol. 44. No. 22. pp. 8709-8715.
GOST all authors (up to 50)
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Goto A., Suzuki T., Ohfuji H., Tanishima M., Fukuda T., Tsujii Y., Kaji H. Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts // Macromolecules. 2011. Vol. 44. No. 22. pp. 8709-8715.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma2014589
UR - https://doi.org/10.1021/ma2014589
TI - Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts
T2 - Macromolecules
AU - Goto, Atsushi
AU - Suzuki, Tomohiro
AU - Ohfuji, Haruki
AU - Tanishima, Miho
AU - Fukuda, Takeshi
AU - Tsujii, Yoshinobu
AU - Kaji, Hironori
PY - 2011
DA - 2011/10/19
PB - American Chemical Society (ACS)
SP - 8709-8715
IS - 22
VL - 44
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Goto,
author = {Atsushi Goto and Tomohiro Suzuki and Haruki Ohfuji and Miho Tanishima and Takeshi Fukuda and Yoshinobu Tsujii and Hironori Kaji},
title = {Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts},
journal = {Macromolecules},
year = {2011},
volume = {44},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ma2014589},
number = {22},
pages = {8709--8715},
doi = {10.1021/ma2014589}
}
Cite this
MLA
Copy
Goto, Atsushi, et al. “Reversible Complexation Mediated Living Radical Polymerization (RCMP) Using Organic Catalysts.” Macromolecules, vol. 44, no. 22, Oct. 2011, pp. 8709-8715. https://doi.org/10.1021/ma2014589.