Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters
Тип публикации: Journal Article
Дата публикации: 2012-05-23
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
We report here metal-free strategies using organocatalysis based on supramolecular recognition for the ring-opening polymerization (ROP) of several cyclic phosphate monomers (CPMs) by a variety of organocatalysts such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), 1,5,7-triazabicyclo[4.4.0]undec-5-ene (TBD), and a bicomponent thiourea–tertiary amine catalyst. Each of these catalysts is efficient to produce linear polyphosphoesters (PPEs) from CPMs but with different sensitivity toward transesterification side reactions. The strong basicity of DBU is sufficient to activate an alcohol initiating the polymerization in the absence of any other cocatalyst. Nevertheless, side chain transfer reactions leading to branched and/or cyclic polymeric structures are observed, especially for high monomer conversion. Unlike DBU, TBD is a dual catalyst activating both the alcohol and the monomer. This dual activation allows shorter polymerization time, but SEC analyses of polyphosphates reveal bimodal molecular weight distr...
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ГОСТ
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Clement B. et al. Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters // Macromolecules. 2012. Vol. 45. No. 11. pp. 4476-4486.
ГОСТ со всеми авторами (до 50)
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Clement B., Grignard B., Koole L., Jérôme C., Lecomte P. Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters // Macromolecules. 2012. Vol. 45. No. 11. pp. 4476-4486.
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TY - JOUR
DO - 10.1021/ma3004339
UR - https://doi.org/10.1021/ma3004339
TI - Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters
T2 - Macromolecules
AU - Clement, Benoit
AU - Grignard, Bruno
AU - Koole, Leo
AU - Jérôme, Christine
AU - Lecomte, Philippe
PY - 2012
DA - 2012/05/23
PB - American Chemical Society (ACS)
SP - 4476-4486
IS - 11
VL - 45
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (до 50 авторов)
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@article{2012_Clement,
author = {Benoit Clement and Bruno Grignard and Leo Koole and Christine Jérôme and Philippe Lecomte},
title = {Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters},
journal = {Macromolecules},
year = {2012},
volume = {45},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ma3004339},
number = {11},
pages = {4476--4486},
doi = {10.1021/ma3004339}
}
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MLA
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Clement, Benoit, et al. “Metal-Free Strategies for the Synthesis of Functional and Well-Defined Polyphosphoesters.” Macromolecules, vol. 45, no. 11, May. 2012, pp. 4476-4486. https://doi.org/10.1021/ma3004339.