Macromolecules, volume 45, issue 17, pages 6807-6818

ROMP Copolymers for Orthogonal Click Functionalizations

Mark Schaefer ¹

Nils Hanik ¹

Andreas F.M. Kilbinger ¹

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Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg, Switzerland |

Publication type: Journal Article

Publication date: 2012-08-22

American Chemical Society (ACS)

Journal: Macromolecules

Quartile SCImago

Quartile WOS

Impact factor: 5.5

ISSN: 00249297, 15205835

DOI: 10.1021/ma301061z

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Materials Chemistry

Organic Chemistry

Inorganic Chemistry

Polymers and Plastics

Abstract

The ring-opening metathesis polymerization using ruthenium carbene initiators developed by Grubbs et al. is one of the most functional group tolerant living polymerization methods known. One of the most used postpolymerization functionalization methods used today is the copper-catalyzed 1,3-dipolar cycloaddition between alkynes and organic azides. Organic azides are, however, not tolerated by ruthenium carbene initiators, and nonprotected alkynes have been shown to slow down the propagation reaction or react with the propagating species leading to broad molecular weight distributions. Here we report the copolymer synthesis of three orthogonally functionalizable monomers: one carrying an activated pentafluorophenyl ester, one a maleimide unit, and a third one a trialkylsilyl-protected alkyne. From these monomers, statistical terpolymers as well as diblock copolymers were synthesized with different molecular weights and monomer compositions or block ratios, respectively. Excellent control over molecular wei...

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Macromolecules	Macromolecules, 11, 18.03% Macromolecules 11 publications, 18.03%
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Polymer	Polymer, 2, 3.28% Polymer 2 publications, 3.28%
Journal of Fluorine Chemistry	Journal of Fluorine Chemistry, 2, 3.28% Journal of Fluorine Chemistry 2 publications, 3.28%
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Biomacromolecules	Biomacromolecules, 2, 3.28% Biomacromolecules 2 publications, 3.28%
Nature Chemistry	Nature Chemistry, 1, 1.64% Nature Chemistry 1 publication, 1.64%
Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 1.64% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 1.64%
Reactive and Functional Polymers	Reactive and Functional Polymers, 1, 1.64% Reactive and Functional Polymers 1 publication, 1.64%
Carbohydrate Polymers	Carbohydrate Polymers, 1, 1.64% Carbohydrate Polymers 1 publication, 1.64%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 1.64% Coordination Chemistry Reviews 1 publication, 1.64%
Chemistry - A European Journal	Chemistry - A European Journal, 1, 1.64% Chemistry - A European Journal 1 publication, 1.64%
Chemical Reviews	Chemical Reviews, 1, 1.64% Chemical Reviews 1 publication, 1.64%
Journal of the American Chemical Society	Journal of the American Chemical Society, 1, 1.64% Journal of the American Chemical Society 1 publication, 1.64%
Journal of Materials Chemistry C	Journal of Materials Chemistry C, 1, 1.64% Journal of Materials Chemistry C 1 publication, 1.64%
RSC Advances	RSC Advances, 1, 1.64% RSC Advances 1 publication, 1.64%
Organic and Biomolecular Chemistry	Organic and Biomolecular Chemistry, 1, 1.64% Organic and Biomolecular Chemistry 1 publication, 1.64%
Green Chemistry	Green Chemistry, 1, 1.64% Green Chemistry 1 publication, 1.64%
Russian Journal of General Chemistry	Russian Journal of General Chemistry, 1, 1.64% Russian Journal of General Chemistry 1 publication, 1.64%
Angewandte Chemie	Angewandte Chemie, 1, 1.64% Angewandte Chemie 1 publication, 1.64%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 1, 1.64% Angewandte Chemie - International Edition 1 publication, 1.64%
Synlett	Synlett, 1, 1.64% Synlett 1 publication, 1.64%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 1.64% Russian Chemical Reviews 1 publication, 1.64%
	2 4 6 8 10 12

Citations by publishers

	2 4 6 8 10 12 14 16 18
American Chemical Society (ACS)	American Chemical Society (ACS), 18, 29.51% American Chemical Society (ACS) 18 publications, 29.51%
Wiley	Wiley, 14, 22.95% Wiley 14 publications, 22.95%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 11, 18.03% Royal Society of Chemistry (RSC) 11 publications, 18.03%
Elsevier	Elsevier, 10, 16.39% Elsevier 10 publications, 16.39%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 3.28% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 3.28%
Springer Nature	Springer Nature, 1, 1.64% Springer Nature 1 publication, 1.64%
Pleiades Publishing	Pleiades Publishing, 1, 1.64% Pleiades Publishing 1 publication, 1.64%
Thieme	Thieme, 1, 1.64% Thieme 1 publication, 1.64%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.64% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.64%
	2 4 6 8 10 12 14 16 18

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Schaefer M., Hanik N., Kilbinger A. F. ROMP Copolymers for Orthogonal Click Functionalizations // Macromolecules. 2012. Vol. 45. No. 17. pp. 6807-6818.

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Schaefer M., Hanik N., Kilbinger A. F. ROMP Copolymers for Orthogonal Click Functionalizations // Macromolecules. 2012. Vol. 45. No. 17. pp. 6807-6818.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ma301061z

UR - https://doi.org/10.1021/ma301061z

TI - ROMP Copolymers for Orthogonal Click Functionalizations

T2 - Macromolecules

AU - Schaefer, Mark

AU - Hanik, Nils

AU - Kilbinger, Andreas F.M.

PY - 2012

DA - 2012/08/22 00:00:00

PB - American Chemical Society (ACS)

SP - 6807-6818

IS - 17

VL - 45

SN - 0024-9297

SN - 1520-5835

ER -

BibTex |

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BibTex Copy

@article{2012_Schaefer,

author = {Mark Schaefer and Nils Hanik and Andreas F.M. Kilbinger},

title = {ROMP Copolymers for Orthogonal Click Functionalizations},

journal = {Macromolecules},

year = {2012},

volume = {45},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/ma301061z},

number = {17},

pages = {6807--6818},

doi = {10.1021/ma301061z}

}

MLA

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MLA Copy

Schaefer, Mark, et al. “ROMP Copolymers for Orthogonal Click Functionalizations.” Macromolecules, vol. 45, no. 17, Aug. 2012, pp. 6807-6818. https://doi.org/10.1021/ma301061z.

Found error?

Publisher

American Chemical Society (ACS)

Journal

Macromolecules

Quartile SCImago

Quartile WOS

Impact factor

5.5

ISSN

00249297 (Print)
15205835 (Electronic)