Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights
Publication type: Journal Article
Publication date: 2014-01-23
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The volume phase transition behavior of well-defined thermally responsive poly(2-methoxyethyl acrylate-co-poly(ethylene glycol) methyl ether acrylate)/poly(N,N′-dimethylacrylamide) (P(MEA-co-PEGA)/PDMA) and poly(N-isopropylacrylamide)/poly(N,N′-dimethylacrylamide) (PNIPAM/PDMA) core–shell nanogels, synthesized via reversible addition–fragmentation chain transfer (RAFT) mediated aqueous dispersion polymerization, is studied and compared by applying FTIR measurements in combination with two-dimensional correlation spectroscopy (2Dcos). Analysis through spectral insights clearly illustrates that the continuous dehydration of the C═O groups in the P(MEA-co-PEGA)/PDMA nanogel core predominates the linear volume phase transition while the hydrogen bonding transformation in the PNIPAM/PDMA nanogel core leads to the abrupt decrease in nanogel size on heating. Additionally, considering the core and the shell separately, the data shows that, for both nanogels, the inner core contributes much more to the volume phas...
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84
Total citations:
84
Citations from 2025:
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(9.52%)
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GOST
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Hou L. et al. Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights // Macromolecules. 2014. Vol. 47. No. 3. pp. 1144-1154.
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Hou L., Ma K., An Z., Wu P. Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights // Macromolecules. 2014. Vol. 47. No. 3. pp. 1144-1154.
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RIS
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TY - JOUR
DO - 10.1021/ma4021906
UR - https://doi.org/10.1021/ma4021906
TI - Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights
T2 - Macromolecules
AU - Hou, Lei
AU - Ma, Kai
AU - An, Zesheng
AU - Wu, Peiyi
PY - 2014
DA - 2014/01/23
PB - American Chemical Society (ACS)
SP - 1144-1154
IS - 3
VL - 47
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Hou,
author = {Lei Hou and Kai Ma and Zesheng An and Peiyi Wu},
title = {Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights},
journal = {Macromolecules},
year = {2014},
volume = {47},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ma4021906},
number = {3},
pages = {1144--1154},
doi = {10.1021/ma4021906}
}
Cite this
MLA
Copy
Hou, Lei, et al. “Exploring the Volume Phase Transition Behavior of POEGA- and PNIPAM-Based Core–Shell Nanogels from Infrared-Spectral Insights.” Macromolecules, vol. 47, no. 3, Jan. 2014, pp. 1144-1154. https://doi.org/10.1021/ma4021906.