Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
Publication type: Journal Article
Publication date: 2014-11-18
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The generation of carbon-centered radicals from alkyl bromides through an oxidative quenching pathway using perylene as an organic visible-light photocatalyst is described. This methodology is used to initiate the radical polymerization of methyl methacrylate and other functionalized vinyl monomers. The polymers possess bromide chain-end groups that can be used to reinitiate polymerization to produce block copolymers. Control over the polymerization propagation can be achieved through pulsed light sequences while the ability to use natural sunlight to promote carbon–carbon bond formation produces polymers with dispersity as low as 1.29.
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324
Total citations:
324
Citations from 2024:
43
(13.27%)
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Miyake G. M., Theriot J. C. Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light // Macromolecules. 2014. Vol. 47. No. 23. pp. 8255-8261.
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Miyake G. M., Theriot J. C. Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light // Macromolecules. 2014. Vol. 47. No. 23. pp. 8255-8261.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma502044f
UR - https://doi.org/10.1021/ma502044f
TI - Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light
T2 - Macromolecules
AU - Miyake, Garret M.
AU - Theriot, Jordan C
PY - 2014
DA - 2014/11/18
PB - American Chemical Society (ACS)
SP - 8255-8261
IS - 23
VL - 47
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
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@article{2014_Miyake,
author = {Garret M. Miyake and Jordan C Theriot},
title = {Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light},
journal = {Macromolecules},
year = {2014},
volume = {47},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ma502044f},
number = {23},
pages = {8255--8261},
doi = {10.1021/ma502044f}
}
Cite this
MLA
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Miyake, Garret M., et al. “Perylene as an Organic Photocatalyst for the Radical Polymerization of Functionalized Vinyl Monomers through Oxidative Quenching with Alkyl Bromides and Visible Light.” Macromolecules, vol. 47, no. 23, Nov. 2014, pp. 8255-8261. https://doi.org/10.1021/ma502044f.