The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions
Publication type: Journal Article
Publication date: 2007-12-19
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The use of a cobalt porphyrin ((TPP)CoCl, 1) in combination with dimethylaminopyridine (DMAP) for the alternating copolymerization of CO2 and epoxide is described. The (TPP)CoCl (1)−DMAP system quantitatively produced the alternating copolymer from CO2 and cyclohexene oxide (CHO) under optimized conditions (50 atm, 80 °C). This calatyst system also worked satisfactorily for the alternating copolymerization of CO2 and a terminal epoxide, e.g., propylene oxide (PO), without formation of cyclic carbonate to give the polycarbonate. The alternating copolymerization of CO2 and epoxide (CHO, PO) was achieved under very mild conditions, such as at ambient temperature and under CO2 at 1 atm, by using the 1−DMAP catalyst system.
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164
Total citations:
164
Citations from 2024:
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(5%)
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Sugimoto H., Kuroda K. The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions // Macromolecules. 2007. Vol. 41. No. 2. pp. 312-317.
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Sugimoto H., Kuroda K. The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions // Macromolecules. 2007. Vol. 41. No. 2. pp. 312-317.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ma702354s
UR - https://doi.org/10.1021/ma702354s
TI - The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions
T2 - Macromolecules
AU - Sugimoto, Hiroshi
AU - Kuroda, Kunitaka
PY - 2007
DA - 2007/12/19
PB - American Chemical Society (ACS)
SP - 312-317
IS - 2
VL - 41
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Sugimoto,
author = {Hiroshi Sugimoto and Kunitaka Kuroda},
title = {The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions},
journal = {Macromolecules},
year = {2007},
volume = {41},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ma702354s},
number = {2},
pages = {312--317},
doi = {10.1021/ma702354s}
}
Cite this
MLA
Copy
Sugimoto, Hiroshi, and Kunitaka Kuroda. “The Cobalt Porphyrin−Lewis Base System: A Highly Selective Catalyst for Alternating Copolymerization of CO2 and Epoxide under Mild Conditions.” Macromolecules, vol. 41, no. 2, Dec. 2007, pp. 312-317. https://doi.org/10.1021/ma702354s.