Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids
Тип публикации: Journal Article
Дата публикации: 2009-07-27
scimago Q1
wos Q1
БС1
SJR: 1.352
CiteScore: 9
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
Chiral complex micelles prepared by 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS) and the poly(ethylene glycol)-block-poly(4-vinylpyridine) (PEG114-b-P4VP61) in the presence of aspartic acid (Asp), tryptophan (Trp), and lysine (Lys) were investigated in aqueous solutions at pH 2.0. TPPS formed J-aggregates in the micellar core. The morphology and optical properties of the complex micelles depended on the properties of amino acids and the preservation time for the mixed solutions of TPPS and amino acids before adding the copolymer. Prolonging the preservation time, the spherical morphology of the complex micelles remained unchanged in the presence of the Asp. On the contrary, a morphology evolution from sphere to rod took place for Trp and Lys. The intensity of the circular dichroism (CD) signals of the complex micelles increase with the preservation time, and the chirality sign was determined by amino acids. l-Trp and l-Lys led to a negative chirality sign and l-Asp a positive one while the corre...
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Zhao L. et al. Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids // Macromolecules. 2009. Vol. 42. No. 16. pp. 6253-6260.
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Zhao L., Wang X., Li Y., Ma R., An Y., Shi L. Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids // Macromolecules. 2009. Vol. 42. No. 16. pp. 6253-6260.
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TY - JOUR
DO - 10.1021/ma900925q
UR - https://doi.org/10.1021/ma900925q
TI - Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids
T2 - Macromolecules
AU - Zhao, Lizhi
AU - Wang, Xin
AU - Li, Yan
AU - Ma, Rujiang
AU - An, Yingli
AU - Shi, Linqi
PY - 2009
DA - 2009/07/27
PB - American Chemical Society (ACS)
SP - 6253-6260
IS - 16
VL - 42
SN - 0024-9297
SN - 1520-5835
ER -
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@article{2009_Zhao,
author = {Lizhi Zhao and Xin Wang and Yan Li and Rujiang Ma and Yingli An and Linqi Shi},
title = {Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids},
journal = {Macromolecules},
year = {2009},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ma900925q},
number = {16},
pages = {6253--6260},
doi = {10.1021/ma900925q}
}
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MLA
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Zhao, Lizhi, et al. “Chiral Micelles of Achiral TPPS and Diblock Copolymer Induced by Amino Acids.” Macromolecules, vol. 42, no. 16, Jul. 2009, pp. 6253-6260. https://doi.org/10.1021/ma900925q.