Macromolecules, volume 43, issue 2, pages 903-908

Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts

Publication typeJournal Article
Publication date2009-12-03
Journal: Macromolecules
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.5
ISSN00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Terpolymerizations of CO2/propylene oxide (PO)/cyclohexene oxide (CHO), CO2/PO/1-hexene oxide (HO), and CO2/PO/1-butene oxide (BO) were carried out without the formation of cyclic carbonates and ether linkages with a cobalt(III) complex of a Salen-type ligand tethered by four quaternary ammonium salts (1). The activities were excellent, in the range of (0.62−1.6) × 106 g/mol-Co (TOF, 4400−14 000 h−1). In all three of terpolymerizations, the data for the PO mole fractions in the feed (fPO) and the polymers (FPO) fit the Fineman−Ross plot well to determine the monomer reactivity ratios. The linear dependencies of the Tg’s of the polymers on the mole fractions of the third monomers (FCHO, FHO, and FBO) were observed with the relationships of “Tg (°C) = 81 × FCHO + 40”, “Tg (°C) = −62 × FHO + 38”, and “Tg (°C) = −27 × FBO + 38”, respectively. The decomposition temperature of the resin increased when the third monomer was employed. The GPC data indicated that the polymer chains grew in an immortal passion from...

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Seong J. E. et al. Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts // Macromolecules. 2009. Vol. 43. No. 2. pp. 903-908.
GOST all authors (up to 50) Copy
Seong J. E., Na S. J., Cyriac A., Kim B., Lee B. Y. Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts // Macromolecules. 2009. Vol. 43. No. 2. pp. 903-908.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/ma902162n
UR - https://doi.org/10.1021/ma902162n
TI - Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts
T2 - Macromolecules
AU - Seong, Jong Eon
AU - Na, Sung Jae
AU - Cyriac, Anish
AU - Kim, Byung-Woo
AU - Lee, Bun Yeoul
PY - 2009
DA - 2009/12/03 00:00:00
PB - American Chemical Society (ACS)
SP - 903-908
IS - 2
VL - 43
SN - 0024-9297
SN - 1520-5835
ER -
BibTex |
Cite this
BibTex Copy
@article{2009_Seong,
author = {Jong Eon Seong and Sung Jae Na and Anish Cyriac and Byung-Woo Kim and Bun Yeoul Lee},
title = {Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts},
journal = {Macromolecules},
year = {2009},
volume = {43},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ma902162n},
number = {2},
pages = {903--908},
doi = {10.1021/ma902162n}
}
MLA
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MLA Copy
Seong, Jong Eon, et al. “Terpolymerizations of CO2, Propylene Oxide, and Various Epoxides Using a Cobalt(III) Complex of Salen-Type Ligand Tethered by Four Quaternary Ammonium Salts.” Macromolecules, vol. 43, no. 2, Dec. 2009, pp. 903-908. https://doi.org/10.1021/ma902162n.
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