Toward Nitroxide-Mediated Photopolymerization
Denis Bertin
1
,
Didier Gigmes
1
,
Davy Louis Versace
2
,
Jacques Lalevee
2
,
Jean‐Pierre Fouassier
2
1
UMR 6264 Laboratoire Chimie Provence, Université de Provence, Avenue Escadrille Normandie-Niemen, Case 542, Marseille 13397, Cedex 20, France
|
Publication type: Journal Article
Publication date: 2010-02-10
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
A new alkoxyamine (methyl 2-((4-benzoylphenyl)((1-methoxy-2-methyl-1-oxopropan-2-yl)oxy)amino)-2-methylpropanoate 4) bearing a chromophore group directly linked to the aminoxyl function is proposed as a photoiniferter. This original compound decomposes under UV irradiation to generate the corresponding alkyl and nitroxide radicals. Drastic changes of the photophysical or photochemical properties of the starting chromophore are noted. Laser flash photolysis experiments showed both a singlet state cleavage and an efficient shortening of the triplet state lifetime of 4. MO calculations suggest a C−O bond homolytic dissociation under UV irradiation through both S1 and T1 pathways. However, an ESR study evidences that both N−O and C−O homolysis occur under UV irradiation. The efficiency of 4 as a conventional photoinitiator is close to that of 2,2′-dimethoxyphenyl acetophenone. When 4 was used as a photoiniferter in nitroxide-mediated photopolymerization (NMP2), a linear growth of the poly(n-butyl acrylate) ch...
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185
Total citations:
185
Citations from 2024:
15
(8.1%)
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GOST
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Guillaneuf Y. et al. Toward Nitroxide-Mediated Photopolymerization // Macromolecules. 2010. Vol. 43. No. 5. pp. 2204-2212.
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Guillaneuf Y., Bertin D., Gigmes D., Versace D. L., Lalevee J., Fouassier J. Toward Nitroxide-Mediated Photopolymerization // Macromolecules. 2010. Vol. 43. No. 5. pp. 2204-2212.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma902774s
UR - https://doi.org/10.1021/ma902774s
TI - Toward Nitroxide-Mediated Photopolymerization
T2 - Macromolecules
AU - Guillaneuf, Yohann
AU - Bertin, Denis
AU - Gigmes, Didier
AU - Versace, Davy Louis
AU - Lalevee, Jacques
AU - Fouassier, Jean‐Pierre
PY - 2010
DA - 2010/02/10
PB - American Chemical Society (ACS)
SP - 2204-2212
IS - 5
VL - 43
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Guillaneuf,
author = {Yohann Guillaneuf and Denis Bertin and Didier Gigmes and Davy Louis Versace and Jacques Lalevee and Jean‐Pierre Fouassier},
title = {Toward Nitroxide-Mediated Photopolymerization},
journal = {Macromolecules},
year = {2010},
volume = {43},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ma902774s},
number = {5},
pages = {2204--2212},
doi = {10.1021/ma902774s}
}
Cite this
MLA
Copy
Guillaneuf, Yohann, et al. “Toward Nitroxide-Mediated Photopolymerization.” Macromolecules, vol. 43, no. 5, Feb. 2010, pp. 2204-2212. https://doi.org/10.1021/ma902774s.