Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts
Publication type: Journal Article
Publication date: 1996-01-01
scimago Q1
wos Q1
SJR: 1.352
CiteScore: 9.0
Impact factor: 5.2
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Ethylene and propylene were copolymerized with 10-undecen-1-ol, using stereorigid Et[Ind]2ZrCl2, Me2Si[Ind]2ZrCl2, Me2Si[2-MeInd]2ZrCl2, and Me2Si[2-Me-4,5-BenzoInd]2ZrCl2 catalysts activated with methylaluminoxane (MAO). As a reference, ethylene copolymerization was also carried out with the nonstereospecific catalyst [Ind]2ZrCl2/MAO. Characterization of the copolymers by 13C and 1H NMR spectroscopy revealed that the polymerization product was a true copolymer and that the conversion of the polar comonomer was strongly favored by the chiral geometry of the catalyst. The pretreatment of 10-undecen-1-ol with MAO before initiating the copolymerization increased the ethylene polymerization rate markedly and slightly improved the reactivity of the polar comonomer. A major improvement in the polymerization rate of 10-undecen-1-ol was obtained when the polymerization temperature and Al/Zr mole ratio were increased.
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Metrics
153
Total citations:
153
Citations from 2024:
9
(5.88%)
The most citing journal
Citations in journal:
17
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GOST
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Aaltonen P. et al. Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts // Macromolecules. 1996. Vol. 29. No. 16. pp. 5255-5260.
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Aaltonen P., Fink G., Löfgren B., Seppälä J. Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts // Macromolecules. 1996. Vol. 29. No. 16. pp. 5255-5260.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ma951607g
UR - https://doi.org/10.1021/ma951607g
TI - Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts
T2 - Macromolecules
AU - Aaltonen, Päivi
AU - Fink, Gerhard
AU - Löfgren, Barbro
AU - Seppälä, J.
PY - 1996
DA - 1996/01/01
PB - American Chemical Society (ACS)
SP - 5255-5260
IS - 16
VL - 29
SN - 0024-9297
SN - 1520-5835
ER -
Cite this
BibTex (up to 50 authors)
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@article{1996_Aaltonen,
author = {Päivi Aaltonen and Gerhard Fink and Barbro Löfgren and J. Seppälä},
title = {Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts},
journal = {Macromolecules},
year = {1996},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ma951607g},
number = {16},
pages = {5255--5260},
doi = {10.1021/ma951607g}
}
Cite this
MLA
Copy
Aaltonen, Päivi, et al. “Synthesis of Hydroxyl Group Containing Polyolefins with Metallocene/Methylaluminoxane Catalysts.” Macromolecules, vol. 29, no. 16, Jan. 1996, pp. 5255-5260. https://doi.org/10.1021/ma951607g.