Macromolecules, volume 30, issue 3, pages 368-372
Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent
1
Chemical Engineering Department, University of Pittsburgh, Pittsburgh, Pennsylvania, and Exxon Research and Engineering Company, Annandale, New Jersey
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Publication type: Journal Article
Publication date: 1997-02-01
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
The copolymerization of 1,2-epoxycyclohexane (cyclohexene oxide, CHO) and carbon dioxide was performed using no other solvent than carbon dioxide itself. A CO2-soluble, ZnO-based catalyst was synthesized and used to catalyze the polymerization. Polymerizations were conducted at different temperatures, pressures, and mole fractions of CHO giving rise to polymer yields as high as 69% with catalyst activities as high as 400 g of polymer/g of Zn. The best results were obtained at temperatures of 100−110 °C and at mole fractions of CHO above XCHO = 0.15. This polymer was >90% polycarbonate with weight average molecular weights (Mw) ranging from 50 000 to 180 000.
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Super M. et al. Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent // Macromolecules. 1997. Vol. 30. No. 3. pp. 368-372.
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Super M., Berluche E., Costello C., Beckman E. Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent // Macromolecules. 1997. Vol. 30. No. 3. pp. 368-372.
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TY - JOUR
DO - 10.1021/ma960755j
UR - https://doi.org/10.1021/ma960755j
TI - Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent
T2 - Macromolecules
AU - Super, Michael
AU - Berluche, Enoch
AU - Costello, Christine
AU - Beckman, Eric
PY - 1997
DA - 1997/02/01
PB - American Chemical Society (ACS)
SP - 368-372
IS - 3
VL - 30
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (up to 50 authors)
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@article{1997_Super,
author = {Michael Super and Enoch Berluche and Christine Costello and Eric Beckman},
title = {Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent},
journal = {Macromolecules},
year = {1997},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ma960755j},
number = {3},
pages = {368--372},
doi = {10.1021/ma960755j}
}
Cite this
MLA
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Super, Michael, et al. “Copolymerization of 1,2-Epoxycyclohexane and Carbon Dioxide Using Carbon Dioxide as Both Reactant and Solvent.” Macromolecules, vol. 30, no. 3, Feb. 1997, pp. 368-372. https://doi.org/10.1021/ma960755j.