Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization
Тип публикации: Journal Article
Дата публикации: 2000-06-23
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.257
CiteScore: 8.8
Impact factor: 5.7
ISSN: 00249297, 15205835
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Краткое описание
The recapping kinetics of a series of unimolecular initiators for free radical polymerization were investigated. The rate constants for the trapping of various carbon-centered radicals were analyzed as a function of structurally different nitroxides in order to determine suitable candidates for living free radical polymerization (LFRP). The technique of laser flash photolysis was used to determine the trapping rate constants for the radicals in the presence of various amounts of nitroxide and to also gain insight into the properties of the LFRP process.
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Skene W. et al. Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization // Macromolecules. 2000. Vol. 33. No. 14. pp. 5065-5072.
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Skene W., Scaiano J., Listigovers N. A., Kazmaier P. M., Georges M. K. Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization // Macromolecules. 2000. Vol. 33. No. 14. pp. 5065-5072.
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TY - JOUR
DO - 10.1021/ma991753c
UR - https://pubs.acs.org/doi/10.1021/ma991753c
TI - Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization
T2 - Macromolecules
AU - Skene, William
AU - Scaiano, J.C
AU - Listigovers, Nancy A
AU - Kazmaier, Peter M
AU - Georges, Michael K.
PY - 2000
DA - 2000/06/23
PB - American Chemical Society (ACS)
SP - 5065-5072
IS - 14
VL - 33
SN - 0024-9297
SN - 1520-5835
ER -
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BibTex (до 50 авторов)
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@article{2000_Skene,
author = {William Skene and J.C Scaiano and Nancy A Listigovers and Peter M Kazmaier and Michael K. Georges},
title = {Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization},
journal = {Macromolecules},
year = {2000},
volume = {33},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/ma991753c},
number = {14},
pages = {5065--5072},
doi = {10.1021/ma991753c}
}
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MLA
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Skene, William, et al. “Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides: Unimolecular Initiators for Living Free Radical Polymerization.” Macromolecules, vol. 33, no. 14, Jun. 2000, pp. 5065-5072. https://pubs.acs.org/doi/10.1021/ma991753c.
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