Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst
Dominik Konkolewicz
1
,
Kristin Schröder
1
,
Johannes Buback
1
,
Stefan Bernhard
1
,
Krzysztof Matyjaszewski
1
Publication type: Journal Article
Publication date: 2012-10-04
scimago Q1
wos Q1
SJR: 1.287
CiteScore: 8.9
Impact factor: 5.2
ISSN: 21611653
PubMed ID:
35607200
Materials Chemistry
Organic Chemistry
Inorganic Chemistry
Polymers and Plastics
Abstract
Photochemically induced ATRP was performed with visible light and sunlight in the presence of parts per million (ppm) copper catalysts. Illumination of the reaction mixture yielded polymerization in case of 392 and 450 nm light but not for 631 nm light. Sunlight was also a viable source for the photoinduced ATRP. Control experiments suggest photoreduction of the CuII complex (ligand to metal charge transfer in the excited state), yielding a CuI complex, and a bromine radical that can initiate polymerization. No photoactivation of CuI complex was detected. This implies that the mechanism of ATRP in the presence of light is a hybrid of ICAR and ARGET ATRP. The method was also used to synthesize block copolymers and polymerizations in water.
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558
Total citations:
558
Citations from 2024:
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(9.5%)
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Konkolewicz D. et al. Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst // ACS Macro Letters. 2012. Vol. 1. No. 10. pp. 1219-1223.
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Konkolewicz D., Schröder K., Buback J., Bernhard S., Matyjaszewski K. Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst // ACS Macro Letters. 2012. Vol. 1. No. 10. pp. 1219-1223.
Cite this
RIS
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TY - JOUR
DO - 10.1021/mz300457e
UR - https://doi.org/10.1021/mz300457e
TI - Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst
T2 - ACS Macro Letters
AU - Konkolewicz, Dominik
AU - Schröder, Kristin
AU - Buback, Johannes
AU - Bernhard, Stefan
AU - Matyjaszewski, Krzysztof
PY - 2012
DA - 2012/10/04
PB - American Chemical Society (ACS)
SP - 1219-1223
IS - 10
VL - 1
PMID - 35607200
SN - 2161-1653
ER -
Cite this
BibTex (up to 50 authors)
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@article{2012_Konkolewicz,
author = {Dominik Konkolewicz and Kristin Schröder and Johannes Buback and Stefan Bernhard and Krzysztof Matyjaszewski},
title = {Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst},
journal = {ACS Macro Letters},
year = {2012},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/mz300457e},
number = {10},
pages = {1219--1223},
doi = {10.1021/mz300457e}
}
Cite this
MLA
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Konkolewicz, Dominik, et al. “Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst.” ACS Macro Letters, vol. 1, no. 10, Oct. 2012, pp. 1219-1223. https://doi.org/10.1021/mz300457e.