Nano Letters, volume 6, issue 4, pages 843-847

Continuous Distribution of Emission States from Single CdSe/ZnS Quantum Dots

Publication typeJournal Article
Publication date2006-03-21
Journal: Nano Letters
scimago Q1
SJR3.411
CiteScore16.8
Impact factor9.6
ISSN15306984, 15306992
PubMed ID:  16608295
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Bioengineering
Abstract
The photoluminescence dynamics of colloidal CdSe/ZnS/streptavidin quantum dots were studied using time-resolved single-molecule spectroscopy. Statistical tests of the photon-counting data suggested that the simple “on/off” discrete state model is inconsistent with experimental results. Instead, a continuous emission state distribution model was found to be more appropriate. Autocorrelation analysis of lifetime and intensity fluctuations showed a nonlinear correlation between them. These results were consistent with the model that charged quantum dots were also emissive, and that time-dependent charge migration gave rise to the observed photoluminescence dynamics.
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