A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate
Publication type: Journal Article
Publication date: 2002-01-01
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
11796067
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[reaction: see text] A general method for the synthesis of alpha-aryl malonates is described. The coupling of an aryl iodide and diethyl malonate in the presence of Cs(2)CO(3) and catalytic amounts of copper(I) iodide and 2-phenylphenol affords the alpha-aryl malonate in good to excellent yields. The mild reaction conditions and high levels of functional group compatibility make this an attractive synthetic alternative to previous methods.
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Metrics
178
Total citations:
178
Citations from 2024:
6
(3.37%)
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GOST
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Hennessy E. J., Buchwald S. L. A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate // Organic Letters. 2002. Vol. 4. No. 2. pp. 269-272.
GOST all authors (up to 50)
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Hennessy E. J., Buchwald S. L. A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate // Organic Letters. 2002. Vol. 4. No. 2. pp. 269-272.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol017038g
UR - https://doi.org/10.1021/ol017038g
TI - A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate
T2 - Organic Letters
AU - Hennessy, Edward J
AU - Buchwald, Stephen L.
PY - 2002
DA - 2002/01/01
PB - American Chemical Society (ACS)
SP - 269-272
IS - 2
VL - 4
PMID - 11796067
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Hennessy,
author = {Edward J Hennessy and Stephen L. Buchwald},
title = {A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate},
journal = {Organic Letters},
year = {2002},
volume = {4},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ol017038g},
number = {2},
pages = {269--272},
doi = {10.1021/ol017038g}
}
Cite this
MLA
Copy
Hennessy, Edward J., and Stephen L. Buchwald. “A General and Mild Copper-Catalyzed Arylation of Diethyl Malonate.” Organic Letters, vol. 4, no. 2, Jan. 2002, pp. 269-272. https://doi.org/10.1021/ol017038g.