Organic Letters

, том 4 , издание 13 , страницы 2277-2280

Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles

Тип публикации: Journal Article

Дата публикации: 2002-06-01

American Chemical Society (ACS)

Organic Letters

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SJR: 1.007

CiteScore: 7.7

Impact factor: 4.7

ISSN: 15237060, 15237052

DOI: 10.1021/ol026149s

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PubMed ID: 12074686

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

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[reaction: see text] A dicobalt hexacarbonyl (Co(2)(CO)(6)) cluster is essential for the unusually broad dipolarophile scope and for the sense and degree of diastereoselection in a catalytic, three-component synthesis of tetrahydrofurans and dihydrofurans. Likely involving a new class of carbonyl ylide, these cycloadditions are stereospecific with respect to the dipolarophile and exhibit high diastereoselectivity and regioselectivity in most cases. Differentiation of all four positions of the tetrahydrofuran can thus be accomplished in a triply convergent manner.

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Skaggs A. J., Lin E. Y., Jamison T. F. Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles // Organic Letters. 2002. Vol. 4. No. 13. pp. 2277-2280.

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TY - JOUR

DO - 10.1021/ol026149s

UR - https://doi.org/10.1021/ol026149s

TI - Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles

T2 - Organic Letters

AU - Skaggs, Aaron J

AU - Lin, Eleanor Y.

AU - Jamison, Timothy F.

PY - 2002

DA - 2002/06/01

PB - American Chemical Society (ACS)

SP - 2277-2280

IS - 13

VL - 4

PMID - 12074686

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2002_Skaggs,

author = {Aaron J Skaggs and Eleanor Y. Lin and Timothy F. Jamison},

title = {Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles},

journal = {Organic Letters},

year = {2002},

volume = {4},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://doi.org/10.1021/ol026149s},

number = {13},

pages = {2277--2280},

doi = {10.1021/ol026149s}

}

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Skaggs, Aaron J., et al. “Cobalt Cluster-Containing Carbonyl Ylides for Catalytic, Three-Component Assembly of Oxygen Heterocycles.” Organic Letters, vol. 4, no. 13, Jun. 2002, pp. 2277-2280. https://doi.org/10.1021/ol026149s.

Издатель

American Chemical Society (ACS)

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Organic Letters

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БС1