Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation
Тип публикации: Journal Article
Дата публикации: 2003-04-04
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
12713309
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Secondary phosphine oxides were prepared from R(1)PCl(2) and R(2)MgBr, followed by hydrolysis. They were obtained in an enantiopure form by preparative chiral HPLC. These new monodentate ligands were tested in the iridium-catalyzed hydrogenation of imines at 25 bar. Enantioselectivities up to 76% were obtained at L/Ir = 2. Addition of pyridine (Pyr/Ir = 1:2) raised the ee to 83%. Using pyridine as an additive allowed reduction of the L/Ir ratio to 1 without reduction of ee. [reaction: see text]
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Для доступа к списку цитирований публикации необходимо авторизоваться.
Топ-30
Журналы
|
2
4
6
8
10
12
14
16
|
|
|
Angewandte Chemie - International Edition
15 публикаций, 8.29%
|
|
|
Angewandte Chemie
15 публикаций, 8.29%
|
|
|
Organometallics
13 публикаций, 7.18%
|
|
|
Tetrahedron Letters
8 публикаций, 4.42%
|
|
|
Journal of the American Chemical Society
8 публикаций, 4.42%
|
|
|
Tetrahedron
7 публикаций, 3.87%
|
|
|
Journal of Organic Chemistry
7 публикаций, 3.87%
|
|
|
European Journal of Organic Chemistry
6 публикаций, 3.31%
|
|
|
Chemistry - A European Journal
6 публикаций, 3.31%
|
|
|
Organic Letters
6 публикаций, 3.31%
|
|
|
Synlett
6 публикаций, 3.31%
|
|
|
Catalysis Science and Technology
5 публикаций, 2.76%
|
|
|
Tetrahedron Asymmetry
4 публикации, 2.21%
|
|
|
Advanced Synthesis and Catalysis
4 публикации, 2.21%
|
|
|
Synthesis
4 публикации, 2.21%
|
|
|
Coordination Chemistry Reviews
3 публикации, 1.66%
|
|
|
Organic and Biomolecular Chemistry
3 публикации, 1.66%
|
|
|
Polyhedron
2 публикации, 1.1%
|
|
|
Journal of Molecular Catalysis A Chemical
2 публикации, 1.1%
|
|
|
ChemCatChem
2 публикации, 1.1%
|
|
|
Inorganic Chemistry
2 публикации, 1.1%
|
|
|
Chemical Reviews
2 публикации, 1.1%
|
|
|
Dalton Transactions
2 публикации, 1.1%
|
|
|
Phosphorus, Sulfur and Silicon and the Related Elements
2 публикации, 1.1%
|
|
|
Beilstein Journal of Organic Chemistry
1 публикация, 0.55%
|
|
|
Chemical and Pharmaceutical Bulletin
1 публикация, 0.55%
|
|
|
Symmetry
1 публикация, 0.55%
|
|
|
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
1 публикация, 0.55%
|
|
|
Mendeleev Communications
1 публикация, 0.55%
|
|
|
2
4
6
8
10
12
14
16
|
Издатели
|
10
20
30
40
50
60
70
|
|
|
Wiley
62 публикации, 34.25%
|
|
|
American Chemical Society (ACS)
39 публикаций, 21.55%
|
|
|
Elsevier
35 публикаций, 19.34%
|
|
|
Royal Society of Chemistry (RSC)
14 публикаций, 7.73%
|
|
|
Georg Thieme Verlag KG
10 публикаций, 5.52%
|
|
|
Taylor & Francis
4 публикации, 2.21%
|
|
|
Springer Nature
3 публикации, 1.66%
|
|
|
Beilstein-Institut
1 публикация, 0.55%
|
|
|
Pharmaceutical Society of Japan
1 публикация, 0.55%
|
|
|
MDPI
1 публикация, 0.55%
|
|
|
The Society of Synthetic Organic Chemistry, Japan
1 публикация, 0.55%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 публикация, 0.55%
|
|
|
The Japan Institute of Heterocyclic Chemistry
1 публикация, 0.55%
|
|
|
10
20
30
40
50
60
70
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
181
Всего цитирований:
181
Цитирований c 2025:
1
(0.55%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
JIANG X. et al. Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation // Organic Letters. 2003. Vol. 5. No. 9. pp. 1503-1506.
ГОСТ со всеми авторами (до 50)
Скопировать
JIANG X., Minnaard A., Hessen B., Feringa B. L., Duchateau A. L. L., Andrien J. G. O., Boogers J. A. F., de Vries J. G. Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation // Organic Letters. 2003. Vol. 5. No. 9. pp. 1503-1506.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/ol034282u
UR - https://doi.org/10.1021/ol034282u
TI - Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation
T2 - Organic Letters
AU - JIANG, XIAO-BIN
AU - Minnaard, Adriaan J.
AU - Hessen, Bart
AU - Feringa, Ben L.
AU - Duchateau, Alexander L. L.
AU - Andrien, Jean G O
AU - Boogers, Jeroen A F
AU - de Vries, Johannes G.
PY - 2003
DA - 2003/04/04
PB - American Chemical Society (ACS)
SP - 1503-1506
IS - 9
VL - 5
PMID - 12713309
SN - 1523-7060
SN - 1523-7052
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2003_JIANG,
author = {XIAO-BIN JIANG and Adriaan J. Minnaard and Bart Hessen and Ben L. Feringa and Alexander L. L. Duchateau and Jean G O Andrien and Jeroen A F Boogers and Johannes G. de Vries},
title = {Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation},
journal = {Organic Letters},
year = {2003},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ol034282u},
number = {9},
pages = {1503--1506},
doi = {10.1021/ol034282u}
}
Цитировать
MLA
Скопировать
JIANG, XIAO-BIN, et al. “Application of Monodentate Secondary Phosphine Oxides, a New Class of Chiral Ligands, in Ir(I)-Catalyzed Asymmetric Imine Hydrogenation.” Organic Letters, vol. 5, no. 9, Apr. 2003, pp. 1503-1506. https://doi.org/10.1021/ol034282u.