Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides
Publication type: Journal Article
Publication date: 2003-03-28
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
12688755
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[reaction: see text] A new synthetic method of chiral beta,beta-disubstituted vinylic sulfoxides bearing various functionalities has been developed by employing Cu-catalyzed conjugate addition of an organozinc reagent to chiral 1-alkynyl sulfoxide. Since the reaction proceeds with very high syn-selectivity, both geometric beta,beta-disubstituted vinylic sulfoxides were stereoselectively synthesized by changing the combination of 1-alkynyl sulfoxide and the organozinc reagent.
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35
Total citations:
35
Citations from 2024:
1
(2%)
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GOST
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Maezaki N. et al. Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides // Organic Letters. 2003. Vol. 5. No. 8. pp. 1345-1347.
GOST all authors (up to 50)
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Maezaki N., Sawamoto H., Yoshigami R., Suzuki T., Tanaka T. Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides // Organic Letters. 2003. Vol. 5. No. 8. pp. 1345-1347.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol034289b
UR - https://doi.org/10.1021/ol034289b
TI - Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides
T2 - Organic Letters
AU - Maezaki, Naoyoshi
AU - Sawamoto, Hiroaki
AU - Yoshigami, Ryoko
AU - Suzuki, Tomoko
AU - Tanaka, Tetsuaki
PY - 2003
DA - 2003/03/28
PB - American Chemical Society (ACS)
SP - 1345-1347
IS - 8
VL - 5
PMID - 12688755
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_Maezaki,
author = {Naoyoshi Maezaki and Hiroaki Sawamoto and Ryoko Yoshigami and Tomoko Suzuki and Tetsuaki Tanaka},
title = {Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides},
journal = {Organic Letters},
year = {2003},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ol034289b},
number = {8},
pages = {1345--1347},
doi = {10.1021/ol034289b}
}
Cite this
MLA
Copy
Maezaki, Naoyoshi, et al. “Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides.” Organic Letters, vol. 5, no. 8, Mar. 2003, pp. 1345-1347. https://doi.org/10.1021/ol034289b.