Organic Letters

, том 5 , издание 13 , страницы 2287-2290

Asymmetric Total Synthesis of Pseurotin A

Тип публикации: Journal Article

Дата публикации: 2003-05-30

American Chemical Society (ACS)

Organic Letters

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SJR: 1.007

CiteScore: 7.7

Impact factor: 4.7

ISSN: 15237060, 15237052

DOI: 10.1021/ol034630s

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PubMed ID: 12816430

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

The asymmetric total syntheses of pseurotin A and 8-O-demethylpseurotin A have been accomplished. Key reactions are a NaH-promoted intramolecular cyclization of an alkynylamide to form a gamma-lactam, an aldol reaction of a benzylidene-substituted ketone, and the late-stage introduction of the benzoyl group by a selective oxidation of a benzylidene moiety with dimethyldioxirane (DMD). [reaction: see text]

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American Chemical Society (ACS)	American Chemical Society (ACS), 13, 24.53% American Chemical Society (ACS) 13 публикаций, 24.53%
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Hayashi Y. et al. Asymmetric Total Synthesis of Pseurotin A // Organic Letters. 2003. Vol. 5. No. 13. pp. 2287-2290.

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Hayashi Y., Shoji M., Yamaguchi S., Mukaiyama T., Yamaguchi J., Kakeya H., OSADA H. Asymmetric Total Synthesis of Pseurotin A // Organic Letters. 2003. Vol. 5. No. 13. pp. 2287-2290.

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TY - JOUR

DO - 10.1021/ol034630s

UR - https://doi.org/10.1021/ol034630s

TI - Asymmetric Total Synthesis of Pseurotin A

T2 - Organic Letters

AU - Hayashi, Yujiro

AU - Shoji, Mitsuru

AU - Yamaguchi, Shinpei

AU - Mukaiyama, Takasuke

AU - Yamaguchi, Junichiro

AU - Kakeya, Hideaki

AU - OSADA, H.

PY - 2003

DA - 2003/05/30

PB - American Chemical Society (ACS)

SP - 2287-2290

IS - 13

VL - 5

PMID - 12816430

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2003_Hayashi,

author = {Yujiro Hayashi and Mitsuru Shoji and Shinpei Yamaguchi and Takasuke Mukaiyama and Junichiro Yamaguchi and Hideaki Kakeya and H. OSADA},

title = {Asymmetric Total Synthesis of Pseurotin A},

journal = {Organic Letters},

year = {2003},

volume = {5},

publisher = {American Chemical Society (ACS)},

month = {may},

url = {https://doi.org/10.1021/ol034630s},

number = {13},

pages = {2287--2290},

doi = {10.1021/ol034630s}

}

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Hayashi, Yujiro, et al. “Asymmetric Total Synthesis of Pseurotin A.” Organic Letters, vol. 5, no. 13, May. 2003, pp. 2287-2290. https://doi.org/10.1021/ol034630s.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

SCImago Q1

Tоп 10% SCImago

WOS Q1

БС1