Organic Letters

, том 5 , издание 24 , страницы 4533-4535

Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation

Тип публикации: Journal Article

Дата публикации: 2003-11-01

American Chemical Society (ACS)

Organic Letters

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wos Q1

БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/ol034848e

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PubMed ID: 14627376

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

[reaction: see text] A novel oxidative photodehydrocyclization of indolinylphenylethenes to a polycyclic heteroaromatic cation with good yields was described. Starting from the trans derivative, the phototransformation is a multistep process. The process includes two photochemical reactions and a trans-cis isomerization reaction, followed by an 1-aza-1,3,5-hexatrienic electrocyclic reaction involving the formation of a C-N bond. The cyclized product gives the stable heteroaromatic cations from hydride elimination with oxygen from air or iodine.

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Львов Андрей

д.х.н.

82 публикации, 1 148 цитирований, 32 рецензии

Индекс Хирша: 21

Иркутский институт химии им. А.Е. Фаворского СО РАН

Иркутский национальный исследовательский технический университет

Области научных интересов

Гетероциклические соединения

Органическая химия

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Федорова О. С. et al. Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation // Organic Letters. 2003. Vol. 5. No. 24. pp. 4533-4535.

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Федорова О. С., Fedorova O. A., Fedorov Y. V., Andryukhina E. N., Fomina M. V., Gromov S. P., Alfimov M. V., Lapouyade R. Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation // Organic Letters. 2003. Vol. 5. No. 24. pp. 4533-4535.

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TY - JOUR

DO - 10.1021/ol034848e

UR - https://pubs.acs.org/doi/10.1021/ol034848e

TI - Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation

T2 - Organic Letters

AU - Федорова, О. С.

AU - Fedorova, Olga A

AU - Fedorov, Yuri V

AU - Andryukhina, Elena N

AU - Fomina, Marina V.

AU - Gromov, Sergey P

AU - Alfimov, Michael V

AU - Lapouyade, René

PY - 2003

DA - 2003/11/01

PB - American Chemical Society (ACS)

SP - 4533-4535

IS - 24

VL - 5

PMID - 14627376

SN - 1523-7060

SN - 1523-7052

ER -

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@article{2003_Федорова,

author = {О. С. Федорова and Olga A Fedorova and Yuri V Fedorov and Elena N Andryukhina and Marina V. Fomina and Sergey P Gromov and Michael V Alfimov and René Lapouyade},

title = {Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation},

journal = {Organic Letters},

year = {2003},

volume = {5},

publisher = {American Chemical Society (ACS)},

month = {nov},

url = {https://pubs.acs.org/doi/10.1021/ol034848e},

number = {24},

pages = {4533--4535},

doi = {10.1021/ol034848e}

}

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Федорова, О. С., et al. “Photochemical Electrocyclization of the Indolinylphenylethenes Involving a C-N Bond Formation.” Organic Letters, vol. 5, no. 24, Nov. 2003, pp. 4533-4535. https://pubs.acs.org/doi/10.1021/ol034848e.