Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS)
Publication type: Journal Article
Publication date: 2003-12-23
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
14723534
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[reaction: see text] Sterically demanding, sulfonated arylphosphines TXPTS and TMAPTS have been applied to the aqueous-phase Heck and Suzuki coupling of aryl bromides. TXPTS provides good yields of Heck coupling products from aryl bromides at 80 degrees C, while both TMAPTS and TPPTS gave significantly less active catalysts. TXPTS is the first ligand to promote the aqueous-phase Heck coupling under such mild conditions. Both TXPTS and TMAPTS provide active catalysts for Suzuki couplings of aryl bromides at 50 degrees C.
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133
Total citations:
133
Citations from 2024:
1
(0.75%)
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Moore L. R., Shaughnessy K. H. Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS) // Organic Letters. 2003. Vol. 6. No. 2. pp. 225-228.
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Moore L. R., Shaughnessy K. H. Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS) // Organic Letters. 2003. Vol. 6. No. 2. pp. 225-228.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol0360288
UR - https://doi.org/10.1021/ol0360288
TI - Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS)
T2 - Organic Letters
AU - Moore, Lucas R
AU - Shaughnessy, Kevin H.
PY - 2003
DA - 2003/12/23
PB - American Chemical Society (ACS)
SP - 225-228
IS - 2
VL - 6
PMID - 14723534
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2003_Moore,
author = {Lucas R Moore and Kevin H. Shaughnessy},
title = {Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS)},
journal = {Organic Letters},
year = {2003},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ol0360288},
number = {2},
pages = {225--228},
doi = {10.1021/ol0360288}
}
Cite this
MLA
Copy
Moore, Lucas R., and Kevin H. Shaughnessy. “Efficient Aqueous-Phase Heck and Suzuki Couplings of Aryl Bromides Using Tri(4,6-dimethyl-3- sulfonatophenyl)phosphine Trisodium Salt (TXPTS).” Organic Letters, vol. 6, no. 2, Dec. 2003, pp. 225-228. https://doi.org/10.1021/ol0360288.