Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties
Publication type: Journal Article
Publication date: 2004-04-01
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
15101742
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[reaction: see text] A series of dendritic ligands with a chiral diphosphine located at the focal point have been synthesized through coupling of pyrphos 2 with Fréchet-type polyether dendron 3. The relationship between the primary structure of the dendrimer and its catalytic properties was established in the Rh-catalyzed asymmetric hydrogenation of alpha-acetamido cinnamic acid 4. A remarkable structural effect on catalytic activity was observed.
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Total citations:
58
Citations from 2025:
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GOST
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YI B. et al. Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties // Organic Letters. 2004. Vol. 6. No. 9. pp. 1361-1364.
GOST all authors (up to 50)
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YI B., Fan Q., Deng G., Li Y., Qiu L. Q., Chan A. S. Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties // Organic Letters. 2004. Vol. 6. No. 9. pp. 1361-1364.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol036512a
UR - https://doi.org/10.1021/ol036512a
TI - Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties
T2 - Organic Letters
AU - YI, BING
AU - Fan, Qing-Hua
AU - Deng, Guo-Jun
AU - Li, Yue-Ming
AU - Qiu, Li Qin
AU - Chan, Albert S.
PY - 2004
DA - 2004/04/01
PB - American Chemical Society (ACS)
SP - 1361-1364
IS - 9
VL - 6
PMID - 15101742
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_YI,
author = {BING YI and Qing-Hua Fan and Guo-Jun Deng and Yue-Ming Li and Li Qin Qiu and Albert S. Chan},
title = {Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties},
journal = {Organic Letters},
year = {2004},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ol036512a},
number = {9},
pages = {1361--1364},
doi = {10.1021/ol036512a}
}
Cite this
MLA
Copy
YI, BING, et al. “Novel Chiral Dendritic Diphosphine Ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Remarkable Structural Effects on Catalytic Properties.” Organic Letters, vol. 6, no. 9, Apr. 2004, pp. 1361-1364. https://doi.org/10.1021/ol036512a.