Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60.
Тип публикации: Journal Article
Дата публикации: 2006-03-01
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
16562917
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
[reaction: see text] A method for one-step preparation of polyfunctionalized fullerene derivatives by regioselective penta-addition of an organocopper reagent is described. A functionalized aryl iodide is first converted to the corresponding Grignard reagent and then to a copper reagent and finally is allowed to react with C(60). The method allows introduction of five functional groups to the C(60) skeleton in a convergent manner. The shuttlecock-like molecules crystallize into a columnar packing structure.
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Zhong Y., MATSUO Y., Nakamura E. Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60. // Organic Letters. 2006. Vol. 8. No. 7. pp. 1463-1466.
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Zhong Y., MATSUO Y., Nakamura E. Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60. // Organic Letters. 2006. Vol. 8. No. 7. pp. 1463-1466.
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TY - JOUR
DO - 10.1021/ol060282t
UR - https://doi.org/10.1021/ol060282t
TI - Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60.
T2 - Organic Letters
AU - Zhong, Yuwu
AU - MATSUO, Yutaka
AU - Nakamura, Eiichi
PY - 2006
DA - 2006/03/01
PB - American Chemical Society (ACS)
SP - 1463-1466
IS - 7
VL - 8
PMID - 16562917
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2006_Zhong,
author = {Yuwu Zhong and Yutaka MATSUO and Eiichi Nakamura},
title = {Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60.},
journal = {Organic Letters},
year = {2006},
volume = {8},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ol060282t},
number = {7},
pages = {1463--1466},
doi = {10.1021/ol060282t}
}
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MLA
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Zhong, Yuwu, et al. “Convergent synthesis of a polyfunctionalized fullerene by regioselective five-fold addition of a functionalized organocopper reagent to C60..” Organic Letters, vol. 8, no. 7, Mar. 2006, pp. 1463-1466. https://doi.org/10.1021/ol060282t.