An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air
Publication type: Journal Article
Publication date: 2007-03-01
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
17346060
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
[structure: see text]. The direct oxidative coupling of benzoic acids with internal alkynes proceeds efficiently in the presence of a rhodium/copper catalyst system under air to afford the corresponding isocoumarin derivatives. The reaction forms no wastes except for water. Under similar conditions, the aerobic coupling with acrylates also takes place smoothly to produce 7-vinylphthalide derivatives via divinylation and subsequent cyclization.
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698
Total citations:
698
Citations from 2024:
29
(4.16%)
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Ueura K., Satoh T., Miura M. An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air // Organic Letters. 2007. Vol. 9. No. 7. pp. 1407-1409.
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Ueura K., Satoh T., Miura M. An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air // Organic Letters. 2007. Vol. 9. No. 7. pp. 1407-1409.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol070406h
UR - https://doi.org/10.1021/ol070406h
TI - An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air
T2 - Organic Letters
AU - Ueura, Kenji
AU - Satoh, Tetsuya
AU - Miura, Masahiro
PY - 2007
DA - 2007/03/01
PB - American Chemical Society (ACS)
SP - 1407-1409
IS - 7
VL - 9
PMID - 17346060
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Ueura,
author = {Kenji Ueura and Tetsuya Satoh and Masahiro Miura},
title = {An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air},
journal = {Organic Letters},
year = {2007},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ol070406h},
number = {7},
pages = {1407--1409},
doi = {10.1021/ol070406h}
}
Cite this
MLA
Copy
Ueura, Kenji, et al. “An Efficient Waste-Free Oxidative Coupling via Regioselective C−H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air.” Organic Letters, vol. 9, no. 7, Mar. 2007, pp. 1407-1409. https://doi.org/10.1021/ol070406h.