Organic Letters, volume 12, issue 5, pages 1000-1003
Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates
Publication type: Journal Article
Publication date: 2010-01-29
Journal:
Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates is achieved by using diglyme as the solvent. The reaction is useful for synthesis of polyfluorobiaryls from readily accessible and nonvolatile polyfluorobenzoate salts. Unlike the Cu-catalyzed decarboxylation cross coupling where oxidative addition is the rate-limiting step, in the Pd-catalyzed version decarboxylation is the rate-limiting step.
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GOST
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Shang R. et al. Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates // Organic Letters. 2010. Vol. 12. No. 5. pp. 1000-1003.
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Shang R., Xu Q., Jiang Y., Wang Y., Liu L. Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates // Organic Letters. 2010. Vol. 12. No. 5. pp. 1000-1003.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol100008q
UR - https://doi.org/10.1021/ol100008q
TI - Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates
T2 - Organic Letters
AU - Shang, Rui
AU - Xu, Qing
AU - Jiang, Yuanye
AU - Wang, Yan
AU - Liu, Lei
PY - 2010
DA - 2010/01/29
PB - American Chemical Society (ACS)
SP - 1000-1003
IS - 5
VL - 12
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex
Copy
@article{2010_Shang,
author = {Rui Shang and Qing Xu and Yuanye Jiang and Yan Wang and Lei Liu},
title = {Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates},
journal = {Organic Letters},
year = {2010},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ol100008q},
number = {5},
pages = {1000--1003},
doi = {10.1021/ol100008q}
}
Cite this
MLA
Copy
Shang, Rui, et al. “Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates.” Organic Letters, vol. 12, no. 5, Jan. 2010, pp. 1000-1003. https://doi.org/10.1021/ol100008q.