Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates
Publication type: Journal Article
Publication date: 2010-01-29
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
20187653
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates is achieved by using diglyme as the solvent. The reaction is useful for synthesis of polyfluorobiaryls from readily accessible and nonvolatile polyfluorobenzoate salts. Unlike the Cu-catalyzed decarboxylation cross coupling where oxidative addition is the rate-limiting step, in the Pd-catalyzed version decarboxylation is the rate-limiting step.
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Metrics
156
Total citations:
156
Citations from 2024:
8
(5.13%)
Cite this
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BibTex |
MLA
Cite this
GOST
Copy
Shang R. et al. Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates // Organic Letters. 2010. Vol. 12. No. 5. pp. 1000-1003.
GOST all authors (up to 50)
Copy
Shang R., Xu Q., Jiang Y., Wang Y., Liu L. Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates // Organic Letters. 2010. Vol. 12. No. 5. pp. 1000-1003.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol100008q
UR - https://doi.org/10.1021/ol100008q
TI - Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates
T2 - Organic Letters
AU - Shang, Rui
AU - Xu, Qing
AU - Jiang, Yuanye
AU - Wang, Yan
AU - Liu, Lei
PY - 2010
DA - 2010/01/29
PB - American Chemical Society (ACS)
SP - 1000-1003
IS - 5
VL - 12
PMID - 20187653
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Shang,
author = {Rui Shang and Qing Xu and Yuanye Jiang and Yan Wang and Lei Liu},
title = {Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates},
journal = {Organic Letters},
year = {2010},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ol100008q},
number = {5},
pages = {1000--1003},
doi = {10.1021/ol100008q}
}
Cite this
MLA
Copy
Shang, Rui, et al. “Pd-Catalyzed Decarboxylative Cross Coupling of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides, and Triflates.” Organic Letters, vol. 12, no. 5, Jan. 2010, pp. 1000-1003. https://doi.org/10.1021/ol100008q.