Boron Asymmetry in a BODIPY Derivative
Publication type: Journal Article
Publication date: 2010-03-17
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
20235590
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A boradiazaindacene (BODIPY) fluorophore with a chirality held on the central boron has been synthesized and the racemate resolved. Dissymetrization of the BODIPY core was obtained by oxidation of the 3-methyl group to the corresponding carboxaldehyde. A hydrogen bond between the aldehyde proton and the fluorine on the boron atom was evidenced by both (1)H NMR and X-ray diffraction. Chiral high-performance liquid chromatography as well as circular dichroism confirm the persistence of both enantiomers.
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104
Total citations:
104
Citations from 2024:
19
(18.27%)
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MLA
Cite this
GOST
Copy
Haefele A. et al. Boron Asymmetry in a BODIPY Derivative // Organic Letters. 2010. Vol. 12. No. 8. pp. 1672-1675.
GOST all authors (up to 50)
Copy
Haefele A., Zedde C., Retailleau P., Ulrich G., Ziessel R. Boron Asymmetry in a BODIPY Derivative // Organic Letters. 2010. Vol. 12. No. 8. pp. 1672-1675.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol100109j
UR - https://doi.org/10.1021/ol100109j
TI - Boron Asymmetry in a BODIPY Derivative
T2 - Organic Letters
AU - Haefele, Alexandre
AU - Zedde, Chantal
AU - Retailleau, Pascal
AU - Ulrich, G.
AU - Ziessel, Raymond
PY - 2010
DA - 2010/03/17
PB - American Chemical Society (ACS)
SP - 1672-1675
IS - 8
VL - 12
PMID - 20235590
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2010_Haefele,
author = {Alexandre Haefele and Chantal Zedde and Pascal Retailleau and G. Ulrich and Raymond Ziessel},
title = {Boron Asymmetry in a BODIPY Derivative},
journal = {Organic Letters},
year = {2010},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ol100109j},
number = {8},
pages = {1672--1675},
doi = {10.1021/ol100109j}
}
Cite this
MLA
Copy
Haefele, Alexandre, et al. “Boron Asymmetry in a BODIPY Derivative.” Organic Letters, vol. 12, no. 8, Mar. 2010, pp. 1672-1675. https://doi.org/10.1021/ol100109j.