Organic Letters, volume 13, issue 1, pages 134-137
Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones
Publication type: Journal Article
Publication date: 2010-11-24
Journal:
Organic Letters
Q1
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Discovering new carbon building blocks is very significant to advance transition-metal-catalyzed cycloadditions for the synthesis of various-sized ring compounds. A new seven-carbon building block from buta-1,3-dienylcyclopropanes (BDCPs) has been developed, showing that, under the catalysis of [Rh(CO)(2)Cl](2), BDCPs react with CO to give [7 + 1] cycloaddition products, cyclooctadienones. The present [7 + 1] reaction provides an efficient entry to the synthetically challenging eight-membered carbocyclic skeleton, which is present in many natural products of medicinal and biological significance.
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Yao Z. K., Li J., Yu Z. Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones // Organic Letters. 2010. Vol. 13. No. 1. pp. 134-137.
GOST all authors (up to 50)
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Yao Z. K., Li J., Yu Z. Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones // Organic Letters. 2010. Vol. 13. No. 1. pp. 134-137.
Cite this
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TY - JOUR
DO - 10.1021/ol102700m
UR - https://doi.org/10.1021/ol102700m
TI - Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones
T2 - Organic Letters
AU - Yao, Zhong Ke
AU - Li, Jianjun
AU - Yu, Zhi-Xiang
PY - 2010
DA - 2010/11/24
PB - American Chemical Society (ACS)
SP - 134-137
IS - 1
VL - 13
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2010_Yao,
author = {Zhong Ke Yao and Jianjun Li and Zhi-Xiang Yu},
title = {Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones},
journal = {Organic Letters},
year = {2010},
volume = {13},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol102700m},
number = {1},
pages = {134--137},
doi = {10.1021/ol102700m}
}
Cite this
MLA
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Yao, Zhong Ke, et al. “Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones.” Organic Letters, vol. 13, no. 1, Nov. 2010, pp. 134-137. https://doi.org/10.1021/ol102700m.