Organic Letters, volume 13, issue 1, pages 134-137

Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones

Publication typeJournal Article
Publication date2010-11-24
Journal: Organic Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.2
ISSN15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Discovering new carbon building blocks is very significant to advance transition-metal-catalyzed cycloadditions for the synthesis of various-sized ring compounds. A new seven-carbon building block from buta-1,3-dienylcyclopropanes (BDCPs) has been developed, showing that, under the catalysis of [Rh(CO)(2)Cl](2), BDCPs react with CO to give [7 + 1] cycloaddition products, cyclooctadienones. The present [7 + 1] reaction provides an efficient entry to the synthetically challenging eight-membered carbocyclic skeleton, which is present in many natural products of medicinal and biological significance.

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GOST Copy
Yao Z. K., Li J., Yu Z. Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones // Organic Letters. 2010. Vol. 13. No. 1. pp. 134-137.
GOST all authors (up to 50) Copy
Yao Z. K., Li J., Yu Z. Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones // Organic Letters. 2010. Vol. 13. No. 1. pp. 134-137.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/ol102700m
UR - https://doi.org/10.1021/ol102700m
TI - Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones
T2 - Organic Letters
AU - Li, Jianjun
AU - Yao, Zhong Ke
AU - Yu, Zhi-Xiang
PY - 2010
DA - 2010/11/24 00:00:00
PB - American Chemical Society (ACS)
SP - 134-137
IS - 1
VL - 13
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex Copy
@article{2010_Yao,
author = {Jianjun Li and Zhong Ke Yao and Zhi-Xiang Yu},
title = {Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones},
journal = {Organic Letters},
year = {2010},
volume = {13},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol102700m},
number = {1},
pages = {134--137},
doi = {10.1021/ol102700m}
}
MLA
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MLA Copy
Yao, Zhong Ke, et al. “Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones.” Organic Letters, vol. 13, no. 1, Nov. 2010, pp. 134-137. https://doi.org/10.1021/ol102700m.
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