Organic Letters, volume 13, issue 19, pages 5366-5369
Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes
Publication type: Journal Article
Publication date: 2011-08-30
Journal:
Organic Letters
Q1
Q1
SJR: 1.245
CiteScore: 9.3
Impact factor: 4.9
ISSN: 15237060, 15237052
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Highly enantioselective (formal) hetero-Diels-Alder reactions between chalcones and formylcyclopropanes are disclosed. The challenging N-heterocyclic carbene (NHC)-bounded enolate intermediates from formylcyclopropanes were captured for new C-C bond forming reactions. The reaction products were obtained with high diastereo- and enantioselectivities and could be easily transformed to optically pure multisubstituted cyclohexane derivatives.
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GOST
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Lv H. et al. Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes // Organic Letters. 2011. Vol. 13. No. 19. pp. 5366-5369.
GOST all authors (up to 50)
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Lv H., Mo J., Fang X., Chi Y. R. Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes // Organic Letters. 2011. Vol. 13. No. 19. pp. 5366-5369.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol202250s
UR - https://doi.org/10.1021/ol202250s
TI - Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes
T2 - Organic Letters
AU - Lv, Hui
AU - Mo, Junming
AU - Fang, Xinqiang
AU - Chi, Yonggui Robin
PY - 2011
DA - 2011/08/30
PB - American Chemical Society (ACS)
SP - 5366-5369
IS - 19
VL - 13
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Lv,
author = {Hui Lv and Junming Mo and Xinqiang Fang and Yonggui Robin Chi},
title = {Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes},
journal = {Organic Letters},
year = {2011},
volume = {13},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/ol202250s},
number = {19},
pages = {5366--5369},
doi = {10.1021/ol202250s}
}
Cite this
MLA
Copy
Lv, Hui, et al. “Formal Diels–Alder Reactions of Chalcones and Formylcyclopropanes Catalyzed by Chiral N-Heterocyclic Carbenes.” Organic Letters, vol. 13, no. 19, Aug. 2011, pp. 5366-5369. https://doi.org/10.1021/ol202250s.