Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener
Publication type: Journal Article
Publication date: 2012-09-04
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
22946672
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The palladium-catalyzed borylation of aryl and heteroaryl halides with a novel borylating agent, tetrakis(dimethylamino)diboron [(Me(2)N)(2)B-B(NMe(2))(2)], is reported. The method is complementary to the previously reported method utilizing bis-boronic acid (BBA) in that certain substrates perform better under one set of optimized reaction conditions than the other. Because tetrakis(dimethylamino)diboron is the synthetic precursor to both BBA and bis(pinacolato)diboron (B(2)Pin(2)), the new method represents a more atom-economical and efficient approach to current borylation methods.
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43
Total citations:
43
Citations from 2024:
4
(9%)
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GOST
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Molander G. A., Trice S. L. J., Kennedy S. M. Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener // Organic Letters. 2012. Vol. 14. No. 18. pp. 4814-4817.
GOST all authors (up to 50)
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Molander G. A., Trice S. L. J., Kennedy S. M. Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener // Organic Letters. 2012. Vol. 14. No. 18. pp. 4814-4817.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol302124j
UR - https://doi.org/10.1021/ol302124j
TI - Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener
T2 - Organic Letters
AU - Molander, Gary A.
AU - Trice, Sarah L J
AU - Kennedy, Steven M
PY - 2012
DA - 2012/09/04
PB - American Chemical Society (ACS)
SP - 4814-4817
IS - 18
VL - 14
PMID - 22946672
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Molander,
author = {Gary A. Molander and Sarah L J Trice and Steven M Kennedy},
title = {Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener},
journal = {Organic Letters},
year = {2012},
volume = {14},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ol302124j},
number = {18},
pages = {4814--4817},
doi = {10.1021/ol302124j}
}
Cite this
MLA
Copy
Molander, Gary A., et al. “Palladium-Catalyzed Borylation of Aryl and Heteroaryl Halides Utilizing Tetrakis(dimethylamino)diboron: One Step Greener.” Organic Letters, vol. 14, no. 18, Sep. 2012, pp. 4814-4817. https://doi.org/10.1021/ol302124j.