An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst.
Тип публикации: Journal Article
Дата публикации: 2013-07-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
PubMed ID:
23815706
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
An amphiphilic macrocyclic compound consisting of 10 tetra-alkyl phosphonium bromide groups and a pillar[5]arene core was prepared. This compound was soluble in both aqueous and organic media and acted as a highly efficient and substrate-selective phase-transfer catalyst. In particular, oxidation of the linear alkene1-hexene to 1-pentanal by KMnO4 was >99%, whereas that of the branched alkene 4-methyl-1-hexene was only 31%, under ideal conditions.
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Ogoshi T., Ueshima N., Yamagishi T. An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst. // Organic Letters. 2013. Vol. 15. No. 14. pp. 3742-3745.
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Ogoshi T., Ueshima N., Yamagishi T. An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst. // Organic Letters. 2013. Vol. 15. No. 14. pp. 3742-3745.
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TY - JOUR
DO - 10.1021/ol4016546
UR - https://doi.org/10.1021/ol4016546
TI - An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst.
T2 - Organic Letters
AU - Ogoshi, Tomoki
AU - Ueshima, Naosuke
AU - Yamagishi, Tada-aki
PY - 2013
DA - 2013/07/01
PB - American Chemical Society (ACS)
SP - 3742-3745
IS - 14
VL - 15
PMID - 23815706
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2013_Ogoshi,
author = {Tomoki Ogoshi and Naosuke Ueshima and Tada-aki Yamagishi},
title = {An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst.},
journal = {Organic Letters},
year = {2013},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ol4016546},
number = {14},
pages = {3742--3745},
doi = {10.1021/ol4016546}
}
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MLA
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Ogoshi, Tomoki, et al. “An amphiphilic pillar[5]arene as efficient and substrate-selective phase-transfer catalyst..” Organic Letters, vol. 15, no. 14, Jul. 2013, pp. 3742-3745. https://doi.org/10.1021/ol4016546.
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