Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution
Publication type: Journal Article
Publication date: 2013-11-19
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
24251964
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A simple and efficient direct radical arylation of unactivated arenes is described which uses cheap and commercially available phenyl hydrazine as an initiator. The reaction occurs through a base promoted homolytic aromatic substitution (BHAS) mechanism involving aryl radicals and aryl radical anions as intermediates and offers a practical approach for preparation of an array of substituted biaryls.
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121
Total citations:
121
Citations from 2024:
14
(11.58%)
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MLA
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GOST
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Dewanji A. et al. Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution // Organic Letters. 2013. Vol. 15. No. 23. pp. 6102-6105.
GOST all authors (up to 50)
Copy
Dewanji A., Murarka S., Curran D. P., Studer A. Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution // Organic Letters. 2013. Vol. 15. No. 23. pp. 6102-6105.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol402995e
UR - https://doi.org/10.1021/ol402995e
TI - Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution
T2 - Organic Letters
AU - Dewanji, Abhishek
AU - Murarka, Sandip
AU - Curran, Dennis P.
AU - Studer, Armido
PY - 2013
DA - 2013/11/19
PB - American Chemical Society (ACS)
SP - 6102-6105
IS - 23
VL - 15
PMID - 24251964
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Dewanji,
author = {Abhishek Dewanji and Sandip Murarka and Dennis P. Curran and Armido Studer},
title = {Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution},
journal = {Organic Letters},
year = {2013},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol402995e},
number = {23},
pages = {6102--6105},
doi = {10.1021/ol402995e}
}
Cite this
MLA
Copy
Dewanji, Abhishek, et al. “Phenyl Hydrazine as Initiator for Direct Arene C–H Arylation via Base Promoted Homolytic Aromatic Substitution.” Organic Letters, vol. 15, no. 23, Nov. 2013, pp. 6102-6105. https://doi.org/10.1021/ol402995e.