Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles
Publication type: Journal Article
Publication date: 2014-11-07
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
25380398
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
The first Ru-catalyzed redox-neutral C-H activation reaction via N-N bond cleavage is reported. Pyrazolidin-3-one is demonstrated as an internally oxidative directing group that enables C-H annulation reactions with a broad scope of alkynes, including previously incompetent terminal alkynes. Pharmacologically privileged 3-(1H-indol-1-yl)propanamides were synthesized in high yields.
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102
Total citations:
102
Citations from 2025:
5
(4.9%)
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MLA
Cite this
GOST
Copy
Zhang Z., Jiang H., Huang Y. Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles // Organic Letters. 2014. Vol. 16. No. 22. pp. 5976-5979.
GOST all authors (up to 50)
Copy
Zhang Z., Jiang H., Huang Y. Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles // Organic Letters. 2014. Vol. 16. No. 22. pp. 5976-5979.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol502998n
UR - https://doi.org/10.1021/ol502998n
TI - Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles
T2 - Organic Letters
AU - Zhang, Zhenxing
AU - Jiang, Hao
AU - Huang, Yong
PY - 2014
DA - 2014/11/07
PB - American Chemical Society (ACS)
SP - 5976-5979
IS - 22
VL - 16
PMID - 25380398
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Zhang,
author = {Zhenxing Zhang and Hao Jiang and Yong Huang},
title = {Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles},
journal = {Organic Letters},
year = {2014},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol502998n},
number = {22},
pages = {5976--5979},
doi = {10.1021/ol502998n}
}
Cite this
MLA
Copy
Zhang, Zhenxing, et al. “Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles.” Organic Letters, vol. 16, no. 22, Nov. 2014, pp. 5976-5979. https://doi.org/10.1021/ol502998n.