Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion
Vitalij V Levin
1
,
Alexey L Trifonov
2
,
Artem A Zemtsov
1
,
Marina I. Struchkova
1
,
Dmitry E. Arkhipov
3, 4
,
1
2
Moscow Chemical Lyceum, Tamozhennyj
proezd, 4, 111033 Moscow, Russian Federation
|
Publication type: Journal Article
Publication date: 2014-11-25
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
25423177
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A method for nucleophilic difluoromethylation of reactive Michael acceptors, aldehydes, and azomethines is described. The reaction is performed using the readily available and air-stable reagent difluoromethylene phosphabetaine. The process involves interaction of an electrophilic substrate with in situ generated difluorinated phosphonium ylide followed by hydrolysis of the carbon-phosphorus bond under mild conditions.
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98
Total citations:
98
Citations from 2025:
3
(3.06%)
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MLA
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GOST
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Levin V. V. et al. Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion // Organic Letters. 2014. Vol. 16. No. 23. pp. 6256-6259.
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Levin V. V., Trifonov A. L., Zemtsov A. A., Struchkova M. I., Arkhipov D. E., Dilman A. D. Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion // Organic Letters. 2014. Vol. 16. No. 23. pp. 6256-6259.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol503225s
UR - https://doi.org/10.1021/ol503225s
TI - Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion
T2 - Organic Letters
AU - Levin, Vitalij V
AU - Trifonov, Alexey L
AU - Zemtsov, Artem A
AU - Struchkova, Marina I.
AU - Arkhipov, Dmitry E.
AU - Dilman, Alexander D
PY - 2014
DA - 2014/11/25
PB - American Chemical Society (ACS)
SP - 6256-6259
IS - 23
VL - 16
PMID - 25423177
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Levin,
author = {Vitalij V Levin and Alexey L Trifonov and Artem A Zemtsov and Marina I. Struchkova and Dmitry E. Arkhipov and Alexander D Dilman},
title = {Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion},
journal = {Organic Letters},
year = {2014},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ol503225s},
number = {23},
pages = {6256--6259},
doi = {10.1021/ol503225s}
}
Cite this
MLA
Copy
Levin, Vitalij V., et al. “Difluoromethylene Phosphabetaine as an Equivalent of Difluoromethyl Carbanion.” Organic Letters, vol. 16, no. 23, Nov. 2014, pp. 6256-6259. https://doi.org/10.1021/ol503225s.
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