Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates
Publication type: Journal Article
Publication date: 2007-09-29
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
17902680
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
We report herein facile acid-catalyzed isomerization of 1-(1'-cycloalkenyl)cyclopropyl sulfonates under mild conditions. The remarkable ease of ring opening is attributed to the presence of a 1'-alkyl substituent. Also included is a palladium-catalyzed ring opening reaction of 1-(1'-cycloalkenyl)cyclopropyl tosylates for convenient preparation of substituted 1,3-dienylamines, which complements previously reported nucleophilic substitution reactions of (1-vinyl)cyclopropyl tosylates.
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GOST
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Quan L. G., Lee H. G., Cha J. K. Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates // Organic Letters. 2007. Vol. 9. No. 22. pp. 4439-4442.
GOST all authors (up to 50)
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Quan L. G., Lee H. G., Cha J. K. Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates // Organic Letters. 2007. Vol. 9. No. 22. pp. 4439-4442.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ol701653x
UR - https://doi.org/10.1021/ol701653x
TI - Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates
T2 - Organic Letters
AU - Quan, Long Guo
AU - Lee, Hyung Goo
AU - Cha, Jin Kun
PY - 2007
DA - 2007/09/29
PB - American Chemical Society (ACS)
SP - 4439-4442
IS - 22
VL - 9
PMID - 17902680
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
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@article{2007_Quan,
author = {Long Guo Quan and Hyung Goo Lee and Jin Kun Cha},
title = {Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates},
journal = {Organic Letters},
year = {2007},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ol701653x},
number = {22},
pages = {4439--4442},
doi = {10.1021/ol701653x}
}
Cite this
MLA
Copy
Quan, Long Guo, et al. “Acid- and Pd(0)-Catalyzed Ring Opening of 1-(1-Cycloalkenyl)cyclopropyl Sulfonates.” Organic Letters, vol. 9, no. 22, Sep. 2007, pp. 4439-4442. https://doi.org/10.1021/ol701653x.