Organic Letters

, том 10 , издание 15 , страницы 3239-3242

Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni₂−Schiff Base Complex

Тип публикации: Journal Article

Дата публикации: 2008-07-09

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

БС1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5

ISSN: 15237060, 15237052

DOI: 10.1021/ol800965t

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PubMed ID: 18610973

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

Direct catalytic asymmetric Mannich-type reactions of β-keto phosphonates are described. A homodinuclear Ni2−Schiff base complex promoted the reaction at 0 °C, giving β-amino phosphonates in up to 90% yield, 20:1 dr, and 99% ee. Control experiments suggested that two Ni metals are important for achieving high yield and stereoselectivity.

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ГОСТ |

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ГОСТ Скопировать

Chen Z. et al. Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2−Schiff Base Complex // Organic Letters. 2008. Vol. 10. No. 15. pp. 3239-3242.

ГОСТ со всеми авторами (до 50) Скопировать

Chen Z., Yakura K., MATSUNAGA S., Shibasaki M. Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2−Schiff Base Complex // Organic Letters. 2008. Vol. 10. No. 15. pp. 3239-3242.

RIS |

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TY - JOUR

DO - 10.1021/ol800965t

UR - https://doi.org/10.1021/ol800965t

TI - Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2−Schiff Base Complex

T2 - Organic Letters

AU - Chen, Zhihua

AU - Yakura, Kenichiro

AU - MATSUNAGA, SHUNJI

AU - Shibasaki, M

PY - 2008

DA - 2008/07/09

PB - American Chemical Society (ACS)

SP - 3239-3242

IS - 15

VL - 10

PMID - 18610973

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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@article{2008_Chen,

author = {Zhihua Chen and Kenichiro Yakura and SHUNJI MATSUNAGA and M Shibasaki},

title = {Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2−Schiff Base Complex},

journal = {Organic Letters},

year = {2008},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/ol800965t},

number = {15},

pages = {3239--3242},

doi = {10.1021/ol800965t}

}

MLA

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MLA Скопировать

Chen, Zhihua, et al. “Direct Catalytic Asymmetric Mannich-Type Reaction of β-Keto Phosphonate Using a Dinuclear Ni2−Schiff Base Complex.” Organic Letters, vol. 10, no. 15, Jul. 2008, pp. 3239-3242. https://doi.org/10.1021/ol800965t.

Издатель

American Chemical Society (ACS)

Журнал

Organic Letters

scimago Q1

wos Q1

БС1

SJR

1.235

CiteScore

8.7

Impact factor

ISSN

15237060 (Print)

15237052 (Electronic)