volume 10 issue 15 pages 3347-3350

1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer

Publication typeJournal Article
Publication date2008-06-27
scimago Q1
wos Q1
SJR1.235
CiteScore8.7
Impact factor5.0
ISSN15237060, 15237052
PubMed ID:  18582073
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Isomeric charge-transfer chromophores using 1,2,3-triazol-diyl as linker have been studied experimentally and computationally. The instability of the polarized reactants precluded the use of the Huisgen reaction and alternative synthetic methodologies were employed. Charge-transfer absorptions between an N,N-dimethylanilino and a dicyanovinyl group are modest to strong, with maxima from lambda(max) = 400 to 453 nm depending on substituent positioning. TD-B3LYP/6-31G(d) calculations are within 0.6 eV of experiment and assign these bands as HOMO-LUMO transitions.
Found 
Found 

Top-30

Journals

1
2
3
4
5
Chemistry - A European Journal
5 publications, 6.25%
Tetrahedron Letters
4 publications, 5%
Journal of Heterocyclic Chemistry
4 publications, 5%
New Journal of Chemistry
4 publications, 5%
Physical Chemistry Chemical Physics
4 publications, 5%
Tetrahedron
3 publications, 3.75%
Chemical Communications
3 publications, 3.75%
Chemistry of Heterocyclic Compounds
2 publications, 2.5%
Dyes and Pigments
2 publications, 2.5%
Optical Materials
2 publications, 2.5%
European Journal of Medicinal Chemistry
2 publications, 2.5%
Journal of Molecular Structure
2 publications, 2.5%
European Journal of Organic Chemistry
2 publications, 2.5%
Journal of the American Chemical Society
2 publications, 2.5%
Journal of Organic Chemistry
2 publications, 2.5%
Organic and Biomolecular Chemistry
2 publications, 2.5%
RSC Advances
2 publications, 2.5%
Journal of the Electrochemical Society
1 publication, 1.25%
Molecules
1 publication, 1.25%
Russian Chemical Bulletin
1 publication, 1.25%
Structural Chemistry
1 publication, 1.25%
Journal of Molecular Liquids
1 publication, 1.25%
Mendeleev Communications
1 publication, 1.25%
Computational and Theoretical Chemistry
1 publication, 1.25%
Angewandte Chemie
1 publication, 1.25%
Angewandte Chemie - International Edition
1 publication, 1.25%
Applied Organometallic Chemistry
1 publication, 1.25%
ChemCatChem
1 publication, 1.25%
Chemistry - An Asian Journal
1 publication, 1.25%
Advanced Energy Materials
1 publication, 1.25%
1
2
3
4
5

Publishers

5
10
15
20
Elsevier
20 publications, 25%
Wiley
19 publications, 23.75%
Royal Society of Chemistry (RSC)
19 publications, 23.75%
American Chemical Society (ACS)
9 publications, 11.25%
Springer Nature
5 publications, 6.25%
Taylor & Francis
2 publications, 2.5%
The Electrochemical Society
1 publication, 1.25%
MDPI
1 publication, 1.25%
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 1.25%
Pleiades Publishing
1 publication, 1.25%
Georg Thieme Verlag KG
1 publication, 1.25%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.25%
5
10
15
20
  • We do not take into account publications without a DOI.
  • Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
80
Share
Cite this
GOST |
Cite this
GOST Copy
Jarowski P. D. et al. 1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer // Organic Letters. 2008. Vol. 10. No. 15. pp. 3347-3350.
GOST all authors (up to 50) Copy
Jarowski P. D., Wu Y. L., Schweizer W., Diederich F. 1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer // Organic Letters. 2008. Vol. 10. No. 15. pp. 3347-3350.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ol801253z
UR - https://doi.org/10.1021/ol801253z
TI - 1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer
T2 - Organic Letters
AU - Jarowski, Peter D.
AU - Wu, Yi Lin
AU - Schweizer, W.
AU - Diederich, Francois
PY - 2008
DA - 2008/06/27
PB - American Chemical Society (ACS)
SP - 3347-3350
IS - 15
VL - 10
PMID - 18582073
SN - 1523-7060
SN - 1523-7052
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Jarowski,
author = {Peter D. Jarowski and Yi Lin Wu and W. Schweizer and Francois Diederich},
title = {1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer},
journal = {Organic Letters},
year = {2008},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ol801253z},
number = {15},
pages = {3347--3350},
doi = {10.1021/ol801253z}
}
MLA
Cite this
MLA Copy
Jarowski, Peter D., et al. “1,2,3-Triazoles as Conjugative π-Linkers in Push−Pull Chromophores: Importance of Substituent Positioning on Intramolecular Charge-Transfer.” Organic Letters, vol. 10, no. 15, Jun. 2008, pp. 3347-3350. https://doi.org/10.1021/ol801253z.