Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities
Тип публикации: Journal Article
Дата публикации: 2008-07-09
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
PubMed ID:
18610974
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Coumarin derivatives that are either cationic (7-ammonium) or neutral (7-hydroxy, 7-methoxy, 6-methyl) form a 1:2 host−guest complex with cucurbit[8]uril (CB[8]). Direct irradiation of these coumarin@CB[8] complexes in water gives head-to-tail (HT) adduct as the major product. The nature of the functional group (polar or nonpolar) at the 6 or 7 position on the coumarin dictates the type of HT adduct (syn- or anti-). It is postulated that the available free volume and the hydrophobic confined environment are responsible for the observed selectivity.
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Barooah N., Pemberton B. C., Sivaguru J. Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities // Organic Letters. 2008. Vol. 10. No. 15. pp. 3339-3342.
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Barooah N., Pemberton B. C., Sivaguru J. Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities // Organic Letters. 2008. Vol. 10. No. 15. pp. 3339-3342.
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TY - JOUR
DO - 10.1021/ol801256r
UR - https://doi.org/10.1021/ol801256r
TI - Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities
T2 - Organic Letters
AU - Barooah, Nilotpal
AU - Pemberton, Barry C
AU - Sivaguru, Jayaraman
PY - 2008
DA - 2008/07/09
PB - American Chemical Society (ACS)
SP - 3339-3342
IS - 15
VL - 10
PMID - 18610974
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2008_Barooah,
author = {Nilotpal Barooah and Barry C Pemberton and Jayaraman Sivaguru},
title = {Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities},
journal = {Organic Letters},
year = {2008},
volume = {10},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ol801256r},
number = {15},
pages = {3339--3342},
doi = {10.1021/ol801256r}
}
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MLA
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Barooah, Nilotpal, et al. “Manipulating Photochemical Reactivity of Coumarins within Cucurbituril Nanocavities.” Organic Letters, vol. 10, no. 15, Jul. 2008, pp. 3339-3342. https://doi.org/10.1021/ol801256r.
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