Organic Letters

, volume 10 , issue 18 , pages 3961-3964

Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability

Victor D. Filimonov ¹

Marina E. Trusova ¹

Pavel S. Postnikov ¹

Elena A Krasnokutskaya ¹

Young Min Lee ¹

Ho Yun Hwang ¹

Hyunuk Kim ¹

Ki-Whan Chi ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Organic Chemistry, Tomsk Polytechnic University, Tomsk 634050 Russia, Department of Chemistry, University of Ulsan, Ulsan 680-749, Republic of Korea, and Department of Chemistry, POSTECH, Pohang 690-784, Republic of Korea

Pohang University of Science and Technology

University of Ulsan

Publication type: Journal Article

Publication date: 2008-08-23

American Chemical Society (ACS)

Organic Letters

scimago Q1

wos Q1

SJR: 1.235

CiteScore: 8.7

Impact factor: 5.0

ISSN: 15237060, 15237052

DOI: 10.1021/ol8013528

Copy DOI

PubMed ID: 18722457

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Abstract

A new, simple, and effective method for the diazotization of a wide range of arylamines has been developed by using a polymer-supported diazotization agent in the presence of p-toluenesulfonic acid. Various pure arenediazonium tosylates with unusual stabilities can be easily prepared by this method. As a result, these salts are useful and versatile substrates for subsequent transformations, such as halogenation and Heck-type reactions. The unusual stabilities of arenediazonium tosylates are also preliminarily discussed with their X-ray structures.

Found

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Filimonov V. D. et al. Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability // Organic Letters. 2008. Vol. 10. No. 18. pp. 3961-3964.

GOST all authors (up to 50) Copy

Filimonov V. D., E. Trusova M., Postnikov P. S., Krasnokutskaya E. A., Lee Y. M., Hwang H. Y., Kim H., Chi K. Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability // Organic Letters. 2008. Vol. 10. No. 18. pp. 3961-3964.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ol8013528

UR - https://doi.org/10.1021/ol8013528

TI - Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability

T2 - Organic Letters

AU - Filimonov, Victor D.

AU - E. Trusova, Marina

AU - Postnikov, Pavel S.

AU - Krasnokutskaya, Elena A

AU - Lee, Young Min

AU - Hwang, Ho Yun

AU - Kim, Hyunuk

AU - Chi, Ki-Whan

PY - 2008

DA - 2008/08/23

PB - American Chemical Society (ACS)

SP - 3961-3964

IS - 18

VL - 10

PMID - 18722457

SN - 1523-7060

SN - 1523-7052

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2008_Filimonov,

author = {Victor D. Filimonov and Marina E. Trusova and Pavel S. Postnikov and Elena A Krasnokutskaya and Young Min Lee and Ho Yun Hwang and Hyunuk Kim and Ki-Whan Chi},

title = {Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability},

journal = {Organic Letters},

year = {2008},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {aug},

url = {https://doi.org/10.1021/ol8013528},

number = {18},

pages = {3961--3964},

doi = {10.1021/ol8013528}

}

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Filimonov, Victor D., et al. “Unusually Stable, Versatile, and Pure Arenediazonium Tosylates: Their Preparation, Structures, and Synthetic Applicability.” Organic Letters, vol. 10, no. 18, Aug. 2008, pp. 3961-3964. https://doi.org/10.1021/ol8013528.