Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand
Тип публикации: Journal Article
Дата публикации: 2008-12-24
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 1.007
CiteScore: 7.7
Impact factor: 4.7
ISSN: 15237060, 15237052
PubMed ID:
19108673
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
A structurally characterized Rh(I) iminocarbene complex (N,C)Rh(CO)Cl is activated with AgOTf to act as a highly cis-selective catalyst for the cyclopropanation of substituted styrenes and other alkenes with ethyl diazoacetate (11 examples, 10-99% yield, up to >99% cis-selectivity).
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Rosenberg M. L., Krivokapic A., Tilset M. Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand // Organic Letters. 2008. Vol. 11. No. 3. pp. 547-550.
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Rosenberg M. L., Krivokapic A., Tilset M. Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand // Organic Letters. 2008. Vol. 11. No. 3. pp. 547-550.
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TY - JOUR
DO - 10.1021/ol802591j
UR - https://doi.org/10.1021/ol802591j
TI - Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand
T2 - Organic Letters
AU - Rosenberg, Marianne Lenes
AU - Krivokapic, Alexander
AU - Tilset, Mats
PY - 2008
DA - 2008/12/24
PB - American Chemical Society (ACS)
SP - 547-550
IS - 3
VL - 11
PMID - 19108673
SN - 1523-7060
SN - 1523-7052
ER -
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@article{2008_Rosenberg,
author = {Marianne Lenes Rosenberg and Alexander Krivokapic and Mats Tilset},
title = {Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand},
journal = {Organic Letters},
year = {2008},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/ol802591j},
number = {3},
pages = {547--550},
doi = {10.1021/ol802591j}
}
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MLA
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Rosenberg, Marianne Lenes, et al. “Highly cis-Selective Cyclopropanations with Ethyl Diazoacetate Using a Novel Rh(I) Catalyst with a Chelating N-Heterocyclic Iminocarbene Ligand.” Organic Letters, vol. 11, no. 3, Dec. 2008, pp. 547-550. https://doi.org/10.1021/ol802591j.
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